benzenethiosulfonic acid S-(4-methoxyphenyl) ester

Base Information

• Chemical Name: benzenethiosulfonic acid S-(4-methoxyphenyl) ester
• CAS No.: 1146-48-1
• Molecular Formula: C₁₃H₁₂O₃S₂
• Molecular Weight: 280.368
• Mol file: 1146-48-1.mol

Synonyms:benzenethiosulfonic acid S-(4-methoxyphenyl) ester

Chemical Property of benzenethiosulfonic acid S-(4-methoxyphenyl) ester

Chemical Property:

Purity/Quality:

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Technology Process of benzenethiosulfonic acid S-(4-methoxyphenyl) ester

There total 18 articles about benzenethiosulfonic acid S-(4-methoxyphenyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-Methoxybenzenethiol (696-63-9) + benzenesufonyl hydrazide (80-17-1) → benzenethiosulfonic acid S-(4-methoxyphenyl) ester (1146-48-1)

Guidance literature:

With tert.-butylhydroperoxide; sodium iodide; In acetonitrile; at 20 ℃; for 12h;

DOI:10.1039/c8ob00244d

Reference yield: 98.0%

4,4'-dimethoxyphenyl disulfide (5335-87-5) + sodium benzenesulfonate (873-55-2) → benzenethiosulfonic acid S-(4-methoxyphenyl) ester (1146-48-1)

Guidance literature:

With iodine; In dichloromethane; for 3h;

DOI:10.1021/acs.orglett.6b01023

Reference yield: 98.0%

4-Methoxybenzenethiol (696-63-9) + sodium benzenesulfonate (873-55-2) → benzenethiosulfonic acid S-(4-methoxyphenyl) ester (1146-48-1)

Guidance literature:

4-Methoxybenzenethiol; With pyridine; iodine; In dichloromethane; at 20 ℃; for 0.0833333h;

sodium benzenesulfonate; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1002/ejoc.201901283

upstream raw materials:

4-methoxybenzenesulfenyl chloride

Benzenesulfinic acid

sodium benzenesulfonate

N-4-methoxyphenylthio-1,4-benzoquonone imine

Downstream raw materials:

(+/-)_S-isopropyl phenylsulfinate

1-(4-methylphenyldisulfanyl)-4-methoxybenzene

4-methoxyphenyl cyclooctyl sulfide

Refernces

• 1、 Kumari, Arram Haritha,Kumar, Jangam Jagadesh,Krishna, Gamidi Rama,Reddy, Raju Jannapu. "Nickel-Catalyzed Difunctionalization of Alkynyl Bromides with Thiosulfonates and N -Arylthio Succinimides: A Convenient Synthesis of 1,2-Thiosulfonylethenes and 1,1-Dithioethenes". supporting information. p. 2850 - 2864. Retrieved 2021/05/18.
• 2、 -. "Preparation method of thiosulfonate compound". Paragraph 0016; 0116-0120. . Retrieved 2021/05/19.