10-Bromodecyl tetrahydropyranyl ether

Base Information

• Chemical Name: 10-Bromodecyl tetrahydropyranyl ether
• CAS No.: 51795-88-1
• Deprecated CAS: 112999-90-3
• Molecular Formula: C15H29 Br O2
• Molecular Weight: 321.298
• Hs Code.: 2932999099
• European Community (EC) Number: 257-425-1
• DSSTox Substance ID: DTXSID60885971
• Nikkaji Number: J294.915F
• Mol file: 51795-88-1.mol

Synonyms:10-Bromodecyl tetrahydropyranyl ether;51795-88-1;EINECS 257-425-1;2H-Pyran, 2-[(10-bromodecyl)oxy]tetrahydro-;2-[(10-BROMODECYL)OXY]TETRAHYDRO-2H-PYRAN;2-((10-Bromodecyl)oxy)tetrahydro-2H-pyran;2H-Pyran, 2-((10-bromodecyl)oxy)tetrahydro-;SCHEMBL2744005;DTXSID60885971;1-bromo-10-[tetrahydropyranyloxy]decane;2-(10-Bromo-decyloxy)-tetrahydro-pyran;1-bromo-10-(2-tetrahydropyranyloxy)decane

Chemical Property of 10-Bromodecyl tetrahydropyranyl ether

Chemical Property:

• Vapor Pressure: 1.65E-05mmHg at 25°C
• Boiling Point: 375.7°C at 760 mmHg
• Flash Point: 139.5°C
• PSA: 18.46000
• Density: 1.13g/cm³
• LogP: 5.04530
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 320.13509
• Heavy Atom Count: 18
• Complexity: 176

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCOC(C1)OCCCCCCCCCCBr

Technology Process of 10-Bromodecyl tetrahydropyranyl ether

There total 11 articles about 10-Bromodecyl tetrahydropyranyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,4-dihydro-2H-pyran (110-87-2) + 1-bromo-10-decanol (53463-68-6) → 1-bromo-10-(tetrahydropyranyloxy)decane (51795-88-1)

Guidance literature:

With toluene-4-sulfonic acid; for 0.5h;

Reference yield: 98.0%

→ 1-bromo-10-(tetrahydropyranyloxy)decane (51795-88-1)

Guidance literature:

Reference yield: 78.0%

10-tetrahydropyranyloxydecanol (43047-93-4) → 1-bromo-10-(tetrahydropyranyloxy)decane (51795-88-1)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 - 20 ℃; for 4h;

DOI:10.1194/jlr.M067033

upstream raw materials:

3,4-dihydro-2H-pyran

1-bromo-10-decanol

1,4-dibromo-butane

(chloro-6' hexyloxy)-2 tetrahydropyranne

Downstream raw materials:

(10-Hydroxydecyl)-triohenylphosphonium-bromid

(14Z,17Z,20Z,23Z,26Z,29Z)-dotriaconta-14,17,20,23,26,29-hexaenoic acid

(2S,3R,14Z)-2-aminooctadec-14-en-3-ol

1-nonadecyl bromide

Refernces

• 1、 Ettmayer, Peter,Billich, Andreas,Baumruker, Thomas,Mechtcheriakova, Diana,Schmid, Heide,Nussbaumer, Peter. "Fluorescence-labeled sphingosines as substrates of sphingosine kinases 1 and 2". . p. 1555 - 1558. Retrieved 2004.
• 2、 Sudhakar, Gangarajula,Kadam, Vilas D.,Reddy, Vaddu V.N.. "Total synthesis of motualevic acids A-E". . p. 1124 - 1125. Retrieved 2010.
• 3、 Schwarz, Meyer,Graminski, G.F.,Waters, R.M.. "Insect Sex Pheromones. Stereospecific Synthesis of (E)-13,13-Dimethyl-11-tetradecen-1-ol Acetate via a Thiophenol-Mediated Olefin Inversion". . p. 260 - 263. Retrieved 1986.
• 4、 Bernstein, Paul S.,Gorusupudi, Aruna,Lucas, Steven,Oberg, Catrina,Rainier, Jon D.,Rallabandi, Rameshu,Wade, Alexander. "The synthesis of the very long chain polyunsaturated fatty acid (VLC-PUFA) 32:6 n-3". supporting information. p. 5563 - 5566. Retrieved 2021/07/02.
• 5、 Chien, Wei-Jynn,Gupta, Sachin,Liu, Bin,Lou, Da Wei,Shen, Yu-Jhe,Syu, Kun-Jie,Tseng, Jui-Chang,Zhang, Yuan-Xin. "Practical Synthesis and Field Application of the Synthetic Sex Pheromone of Rice Stem Borer, Chilo suppressalis (Lepidoptera: Pyralidae)". . . Retrieved 2020/03/11.