IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3

Base Information

• Chemical Name: IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3
• CAS No.: 383910-23-4
• Molecular Formula: C₃₆H₅₄IN₃U
• Molecular Weight: 893.778
• Mol file: 383910-23-4.mol

Synonyms:IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3

Chemical Property of IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3

There total 1 articles about IU(N(C(CH₃)3)(C₆H₃(CH₃)2))3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

UI3(tetrahydrofuran)4 (115450-92-5) + lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate (260265-93-8) → IU(N(C(CH3)3)(C6H3(CH3)2))3 (383910-23-4)

Guidance literature:

In toluene; byproducts: LiI, reduced U(0); at -90 to 0°C;

DOI:10.1021/ja980095t

Reference yield: 80.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + IU(N(C(CH3)3)(C6H3(CH3)2))3 (383910-23-4) → U(THF)(N(t-Bu)Ph)3 (331731-01-2)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; react. for 20 mins.;

DOI:10.1021/ja980095t

Reference yield: 79.6%

IU(N(C(CH3)3)(C6H3(CH3)2))3 (383910-23-4) + tris(trimethylsilyl)silyl lithium * 3 tetrahydrofuran → Si(Si(CH3)3)3U(N(C4H9)C6H3(CH3)2)3

Guidance literature:

In diethyl ether; a soln. of Li-compound in diethyl ether was added to a frozen soln. of U-complex in diethyl ether, the mixt. was stirred for 10.5 h at room temp.; the volatiles were removed, solid was extd. with diethyl ether, filtered, concd., recrystd. at -30°C; elem. anal.;

DOI:10.1021/om010575k

upstream raw materials:

UI₃(tetrahydrofuran)4

lithium N-(3,5-dimethylphenyl)-tert-butylamide etherate

Downstream raw materials:

(μ-benzene-d6)[U(N[C(CH3)3](3,5-C6H3Me2))2]2

U(THF)(N(t-Bu)Ph)3

(μ-toluene)[U(N[C(CH3)3](3,5-C6H3Me2))2]2

(μ-toluene-d8)[U(N[C(CH3)3](3,5-C6H3Me2))2]2

Refernces