CID 4328639

Base Information

• Chemical Name: CID 4328639
• CAS No.: 2923-28-6
• Molecular Formula: CF3HSO3Ag
• Molecular Weight: 256.939
• Hs Code.: 28432900
• Mol file: 2923-28-6.mol

Synonyms:SCHEMBL19713108

Chemical Property of CID 4328639

Chemical Property:

• Appearance/Colour: light beige crystalline powder
• Vapor Pressure: 1.14mmHg at 25°C
• Melting Point: 286 °C(lit.)
• Boiling Point: 162ºC at 760mmHg
• PSA: 65.58000
• Density: 1.876g/cm3
• LogP: 1.13220
• Storage Temp.: 2-8°C
• Sensitive.: Light Sensitive
• Solubility.: Methanol (Slightly), Water (Slightly)
• Water Solubility.: Soluble in water and also in most organic solvents.
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 256.86494
• Heavy Atom Count: 9
• Complexity: 163

Purity/Quality:

99% ^*data from raw suppliers

Silver trifluoromethanesulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi; C
• Hazard Codes: Xi,C
• Statements: 36/37/38-50-34
• Safety Statements: 26-36-61-45-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)O.[Ag]
• Uses: Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.

Technology Process of CID 4328639

There total 7 articles about CID 4328639 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trifluorormethanesulfonic acid (1493-13-6) + silver(l) oxide (20667-12-3) → silver trifluoromethanesulfonate (2923-28-6)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1039/c3dt52416g

Reference yield: 80.0%

silver(I) acetate (563-63-3) + [(CH3)3C2H2N3](2+)*2CF3SO3(1-)=[(CH3)3C2H2N3](CF3SO3)2 → bis(N,N',N''-trimethyl-1,2,4-triazolium)silver(CF3SO3)3 + silver trifluoromethanesulfonate (2923-28-6)

Guidance literature:

In tetrahydrofuran; byproducts: CH3COOH; under Ar, one equiv. AgOOCCH3, reflux for 3 h; white powder was pptd., washed several times with THF;

DOI:10.1016/S0022-328X(00)00037-1

Reference yield:

Ag2 O + trifluorormethanesulfonic acid (1493-13-6) → silver trifluoromethanesulfonate (2923-28-6)

Guidance literature:

In C₆ H₆; acetonitrile;

upstream raw materials:

trifluorormethanesulfonic acid

silver(l) oxide

silver(I) acetate

Downstream raw materials:

isopropyl triflate

allyl triflate

triphenylsilyl trifluoromethanesulfonate

4-Methylbenzoesaeure-trifluormethansulfonsaeure-anhydrid

Refernces

• 1、 Guerret, Olivier,Solé, Stéphane,Gornitzka, Heinz,Trinquier, Georges,Bertrand, Guy. "1,2,4-Triazolium-5-ylidene and 1,2,4-triazol-3,5-diylidene as new ligands for transition metals". . p. 112 - 117. Retrieved 2000.
• 2、 Ratjen, Lars,Vantomme, Ghislaine,Lehn, Jean-Marie. "Strain-Induced Reactivity in the Dynamic Covalent Chemistry of Macrocyclic Imines". supporting information. p. 10070 - 10081. Retrieved 2015/07/07.