5H-Dibenzarsenole, 5-chloro-

Base Information

• Chemical Name: 5H-Dibenzarsenole, 5-chloro-
• CAS No.: 2866-58-2
• Molecular Formula: C12H8 As Cl
• Molecular Weight: 262.57
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID80182818
• Nikkaji Number: J39.186G
• Wikidata: Q83053520
• Mol file: 2866-58-2.mol

Synonyms:5H-Dibenzarsenole, 5-chloro-;2866-58-2;TL 64;5-Chloro-5H-dibenzarsenole;BRN 0142612;9-CHLORODIBENZOARSENOLE;4-27-00-09762 (Beilstein Handbook Reference);C12H8AsCl;9-chloro-9-arsafluorene;5-Chloro-5H-dibenzarsole;C12-H8-As-Cl;5H-Dibenzarsole, 5-chloro-;DTXSID80182818;LS-60346

Chemical Property of 5H-Dibenzarsenole, 5-chloro-

Chemical Property:

• PSA: 0.00000
• LogP: 2.01150
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 261.953048
• Heavy Atom Count: 14
• Complexity: 196

Purity/Quality:

5-CHLORO-5H-DIBENZARSENOLE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3[As]2Cl

Technology Process of 5H-Dibenzarsenole, 5-chloro-

There total 6 articles about 5H-Dibenzarsenole, 5-chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.4%

biphenyl (92-52-4,1594-86-1) → 9-chlorobiphenylenearsine (2866-58-2) + p-biphenylyldichloroarsine (109832-50-0) + m-biphenylyldichloroarsine (109832-49-7)

Guidance literature:

With arsenic trichloride; aluminum tri-bromide; tin(IV) chloride; for 168h;

Reference yield: 28.9%

biphenyl (92-52-4,1594-86-1) → 9-chlorobiphenylenearsine (2866-58-2) + m-biphenylyldichloroarsine (109832-49-7)

Guidance literature:

With arsenic trichloride; sulfuric acid; aluminium trichloride; for 6.5h; Heating;

Reference yield:

biphenyl (92-52-4,1594-86-1) → 9-chlorobiphenylenearsine (2866-58-2)

Guidance literature:

With aluminium trichloride; arsenic trichloride; at 165 - 185 ℃;

DOI:10.1021/ja01365a049

upstream raw materials:

biphenyl

2,2'-diiodobiphenyl

Downstream raw materials:

9-phenyl-9-arsafluorene

5-p-tolyl-5H-dibenzarsole

9-iodo-9-arsafluorene

5-oxo-5H-5λ⁵-dibenzarsol-5-ol

Refernces

• 1、 Yaroshevskii, A. B.,Gavrilov, V. I.. "CYCLIZATION OF BIPHENYL". . p. 1885 - 1887. Retrieved 2007/10/02.