biphenyl-2,3-dicarboxylic acid dimethyl ester

Base Information

• Chemical Name: biphenyl-2,3-dicarboxylic acid dimethyl ester
• CAS No.: 50402-81-8
• Molecular Formula: C₁₆H₁₄O₄
• Molecular Weight: 270.285
• Mol file: 50402-81-8.mol

Synonyms:biphenyl-2,3-dicarboxylic acid dimethyl ester

Chemical Property of biphenyl-2,3-dicarboxylic acid dimethyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of biphenyl-2,3-dicarboxylic acid dimethyl ester

There total 4 articles about biphenyl-2,3-dicarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

lauryl acrylate (2156-97-0) + dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate (192884-89-2,1013643-92-9) → 1-dodecyl propionate (6221-93-8) + biphenyl-2,3-dicarboxylic acid dimethyl ester (50402-81-8)

Guidance literature:

With palladium 10% on activated carbon; In water; at 120 ℃; for 6h;

DOI:10.1039/c7gc03819d

Reference yield: 66.0%

(E)-buta-1,3-dienylbenzene (16939-57-4) + dimethyl acetylenedicarboxylate (762-42-5) → biphenyl-2,3-dicarboxylic acid dimethyl ester (50402-81-8) + C16H20O4

Guidance literature:

(E)-buta-1,3-dienylbenzene; dimethyl acetylenedicarboxylate; at 50 ℃; for 12h; Inert atmosphere;

With palladium 10% on activated carbon; In water; at 120 ℃; Inert atmosphere;

DOI:10.1039/c7gc03819d

Reference yield: 66.0%

dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate (192884-89-2,1013643-92-9) → biphenyl-2,3-dicarboxylic acid dimethyl ester (50402-81-8) + C16H20O4

Guidance literature:

With palladium 10% on activated carbon; In toluene; at 120 ℃; for 6h; Reagent/catalyst; Solvent; Catalytic behavior; Inert atmosphere;

DOI:10.1039/c7gc03819d

upstream raw materials:

(E)-3-phenylpropenal

lauryl acrylate

dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate

(E)-buta-1,3-dienylbenzene

Downstream raw materials:

1,3-dihydro-4-phenylisobenzofuran

2-Nitro-4-Phenyl indane-1,3-dione

Refernces