n-Propyl acrylate

Base Information

• Chemical Name: n-Propyl acrylate
• CAS No.: 925-60-0
• Deprecated CAS: 2056117-88-3
• Molecular Formula: C6H10 O2
• Molecular Weight: 114.144
• Hs Code.: 2916129000
• European Community (EC) Number: 213-120-5
• NSC Number: 32620
• UNII: T23G14902U
• DSSTox Substance ID: DTXSID6061288
• Nikkaji Number: J82.108J
• Wikidata: Q15726115
• Mol file: 925-60-0.mol

Synonyms:n-Propyl acrylate;925-60-0;Propyl acrylate;Propyl 2-propenoate;2-PROPENOIC ACID, PROPYL ESTER;Acrylic acid, propyl ester;propyl prop-2-enoate;Allyln-propylether;24979-82-6;CCRIS 8584;UNII-T23G14902U;HSDB 5443;EINECS 213-120-5;NSC 32620;NSC-32620;T23G14902U;n-Propyl acrylate, 95%, stab. with 0.1% 4-methoxyphenol;Propylacrylate;n-propylacrylate;1-Propyl acrylate;Acrylic acid propyl;Acrylic acid n-propyl ester;SCHEMBL14982;PROPYL ACRYLATE [HSDB];DTXSID6061288;(C6-H10-O2)x;NSC32620;MFCD00048693;AKOS009031515;FT-0693883;Q15726115

Chemical Property of n-Propyl acrylate

Chemical Property:

• Boiling Point: 120.9°Cat760mmHg
• Flash Point: 26.1°C
• PSA: 26.30000
• Density: 0.904g/cm³
• LogP: 1.12560
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 114.068079557
• Heavy Atom Count: 8
• Complexity: 86.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S16:Keep away from sources of ignition - No smoking.; S26:In case of contact with eyes, rinse immediately with plenty of

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Esters, Other
• Canonical SMILES: CCCOC(=O)C=C

Technology Process of n-Propyl acrylate

There total 10 articles about n-Propyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

propan-1-ol (71-23-8) + acrylic acid (79-10-7) → n-propyl acrylate (925-60-0)

Guidance literature:

With toluene-4-sulfonic acid; at 60 ℃; for 24h; Neat (no solvent);

DOI:10.1016/j.ejmech.2011.06.036

Reference yield: 55.0%

propan-1-ol (71-23-8) + acryloyl chloride (814-68-6,25189-84-8) → n-propyl acrylate (925-60-0)

Guidance literature:

With triethylamine; In diethyl ether; for 16h; Ambient temperature;

DOI:10.1016/S0040-4020(01)80893-0

Reference yield: 33.0%

→ n-propyl acrylate (925-60-0)

Guidance literature:

With [1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene]copper (I) fluoride; tetrabutyl-ammonium chloride; In tetrahydrofuran; at 80 ℃; for 18h;

upstream raw materials:

2-acetoxy-propionic acid propyl ester

2,3-dibromo-propionic acid propyl ester

propan-1-ol

acrylic acid methyl ester

Refernces

• 1、 -. "Method for synthesizing low-carbon alcohol acrylate from acetylene through carbonylation". Paragraph 0039; 0040. . Retrieved 2018/05/30.
• 2、 Silva, Fabio P.L.,De Assis, Priscilla A.C.,Junior, Claudio G.L.,De Andrade, Natalia G.,Da Cunha, Saraghina M.D.,Oliveira, Marcia R.,Vasconcellos, Mario L.A.A.. "Synthesis, evaluation against Leishmania amazonensis and cytotoxicity assays in macrophages of sixteen new congeners Morita-Baylis-Hillman adducts". experimental part. p. 4295 - 4301. Retrieved 2011/11/13.