Samarium(3+);triiodide

Base Information

• Chemical Name: Samarium(3+);triiodide
• CAS No.: 13813-25-7
• Molecular Formula: I3Sm
• Molecular Weight: 531.073
• Nikkaji Number: J134.358K
• Mol file: 13813-25-7.mol

Synonyms:samarium(3+);triiodide;Samarium(iii)iodide;XQKBFQXWZCFNFF-UHFFFAOYSA-K

Chemical Property of Samarium(3+);triiodide

Chemical Property:

• Melting Point: 850°C
• Boiling Point: 127°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.65710
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 532.6332
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Samarium(III) iodide anhydrous, powder ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [I-].[I-].[I-].[Sm+3]

Technology Process of Samarium(3+);triiodide

There total 13 articles about Samarium(3+);triiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Sm(water)9](I)3 → samarium(III) iodide (13813-25-7)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Sm compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 95.0%

samarium diiodide (32248-43-4) + 1,3,5,7-cycloocatetraene → samarium(III) iodide (13813-25-7) + iodo(η8-cyclooctatetraene)(tetrahydrofuran)samarium (126075-48-7)

Guidance literature:

With tetrahydrofurane; In tetrahydrofuran; Ar; few min;; soln. concd.; crystd.;;

DOI:10.1016/0022-328X(94)80108-8

Reference yield: 77.0%

samarium (7440-19-9) + mercury(II) iodide → samarium(III) iodide (13813-25-7) + samarium diiodide(tetrahydrofuran)2 + mercury

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; React. of HgI2 with excess Sm under N2 in refluxing THF gives yellow (SmI3) and grey (Hg) suspn. in 0.5 h, a blue-green colour (SmI2) develops, heating (8 h).; Filtn., evapn.;

DOI:10.1246/cl.1999.837

upstream raw materials:

aluminium(III) iodide

hydrogen iodide

samarium

iodine

Downstream raw materials:

samarium diiodide

[(2,5-bis(N-(2,6-diisopropylphenyl)iminomethyl)pyrrolyl)SmI₂(thf)]2

Sm(C₆H₅N₂C₃(CH₃)2(CHO)O)4I₂⁽¹⁺⁾*I^(1-)=[Sm(C₆H₅N₂C₃(CH₃)2(CHO)O)4I₂]I

[Sm(C₁₇H₁₆N₄O₃)2I₂]⁽¹⁺⁾*I^(1-) = [Sm(C₁₇H₁₆N₄O₃)2I₂]I

Refernces

• 1、 Deng, Daoli,Qian, Changtao,Song, Fuquan,Wang, Zhaoyu,Wu, Guang,et al.. "Studies on organolanthanoid complexes LI. Syntheses of bis- and tris(2-methoxyethylcyclopentadienyl) lanthanoid complexes and crystal structures of bis(2-methoxyethylcyclopentadienyl)ytterbium iodide and tris(2-methoxyethylcyclopentadienyl)samarium". . p. 83 - 88. Retrieved 1993.
• 2、 Boyle, Timothy J.,Ottley, Leigh Anna M.,Alam, Todd M.,Rodriguez, Mark A.,Yang, Pin,Mcintyre, Sarah K.. "Structural characterization of methanol substituted lanthanum halides". . p. 1784 - 1795. Retrieved 2010/07/03.
• 3、 Astakhova,Goryushkin. "X-ray powder diffraction study of samarium iodide". . p. 1551 - 1553. Retrieved 2008/10/08.