Triphenylstannanylium;fluoride

Base Information

• Chemical Name: Triphenylstannanylium;fluoride
• CAS No.: 379-52-2
• Molecular Formula: C18H15 F Sn
• Molecular Weight: 369.026
• Hs Code.: 2903999090
• Mol file: 379-52-2.mol

Synonyms:SCHEMBL1032385;AKOS025295252

Chemical Property of Triphenylstannanylium;fluoride

Chemical Property:

• Vapor Pressure: 8.22E-06mmHg at 25°C
• Melting Point: 281 °C
• Boiling Point: 385.8°Cat760mmHg
• Flash Point: 187.1°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.62300
• Sensitive.: moisture sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 370.017981
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

99.9% ^*data from raw suppliers

Triphenyltin fluoride 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 23/24/25-50/53
• Safety Statements: 36/37/39-45-61-60-28-27-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+](C2=CC=CC=C2)C3=CC=CC=C3.[F-]

Technology Process of Triphenylstannanylium;fluoride

There total 14 articles about Triphenylstannanylium;fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

triphenyltin chloride (639-58-7) → triphenyltinfluoride (379-52-2)

Guidance literature:

With potassium fluoride; In ethanol; water; fluoride in water was added to tin-compd. in ethanol, refluxed with stirring for 4 h, cooled; filtered off, dried in air; NMR;

DOI:10.1016/0022-328X(91)86380-9

Reference yield: 83.17%

tetrachloromethane (56-23-5) + 2-methylene-1,3-propanediylbis (86854-53-7) → triphenyltinfluoride (379-52-2) + 1,1,1,5,5,5-hexachloro-3-methylenepentane (86854-56-0) + (4,4,4-trichloro-2-methylenebutyl)triphenylstannane (86854-55-9)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); at 70 ℃; for 60h;

DOI:10.1021/jo00169a042

Reference yield: 60.0%

fluoroiodomethane (373-53-5) + dibutylchloro(phenyl)stannane (13361-98-3) → dibutyl(fluoroiodomethyl)(phenyl)stannane + triphenyltinfluoride (379-52-2)

Guidance literature:

fluoroiodomethane; With lithium diisopropyl amide; In tetrahydrofuran; at -40 ℃; for 2.27778E-05h; Flow reactor;

dibutylchloro(phenyl)stannane; In tetrahydrofuran; at -40 ℃; for 0.00290833h; chemoselective reaction; Flow reactor;

DOI:10.1002/anie.202003831

upstream raw materials:

tetrachloromethane

2-methylene-1,3-propanediylbis

potassium fluoride

triphenyltin chloride

Downstream raw materials:

diphenyl methyl tin bromide

methyldiphenyltin(IV) iodide

phenyltin trichloride

diphenyl methyl tin chloride

Refernces

• 1、 Colella, Marco,Degennaro, Leonardo,Higuma, Ryosuke,Ishikawa, Susumu,Luisi, Renzo,Nagaki, Aiichiro,Takahashi, Yusuke,Tota, Arianna. "Fluoro-Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors". supporting information. p. 10924 - 10928. Retrieved 2020/05/08.
• 2、 Altmann, Reiner,Jurkschat, Klaus,Schürmann, Markus,Dakternieks, Dainis,Duthie, Andrew. "Methylene-bridged tri- and tetratin compounds as Lewis acids". . p. 5716 - 5723. Retrieved 2008/10/08.