Technology Process of N,N-diallyl-2-bromobenzenesulfonamide
There total 1 articles about N,N-diallyl-2-bromobenzenesulfonamide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
Grubbs catalyst first generation;
In
dichloromethane;
at 20 ℃;
for 15h;
DOI:10.1021/ol0480123
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 95 percent / di(tricyclohexylphosphine)(benzylidene)ruthenium dichloride / CH2Cl2 / 15 h / 20 °C
2.1: 87 percent / Pd(OAc)2; triphenylphosphine; K2CO3 / dimethylformamide / 15 h / 110 °C
3.1: 93 percent / H2 / Pd/C / ethanol / 15 h / 20 °C
4.1: lithium; NH3 / tetrahydrofuran / 4.5 h / -78 °C
4.2: 90 percent / NH4Cl / tetrahydrofuran / 16 h / -78 - 20 °C
With
palladium diacetate; Grubbs catalyst first generation; ammonia; hydrogen; lithium; potassium carbonate; triphenylphosphine;
palladium on activated charcoal;
In
tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;
1.1: ring-closing alkene metathesis / 2.1: Heck reaction;
DOI:10.1021/ol0480123
