9H-carbazol-9-amine

Base Information

• Chemical Name: 9H-carbazol-9-amine
• CAS No.: 17223-85-7
• Molecular Formula: C12H10 N2
• Molecular Weight: 182.225
• Hs Code.: 2933990090
• European Community (EC) Number: 811-558-7
• NSC Number: 123514
• DSSTox Substance ID: DTXSID00298501
• Nikkaji Number: J324.897F
• Wikidata: Q72434101
• Mol file: 17223-85-7.mol

Synonyms:9H-carbazol-9-amine;17223-85-7;carbazol-9-amine;9-Aminocarbazole;n-aminocarbazole;Oprea1_406257;SCHEMBL257566;DTXSID00298501;CGTWOOPTAAXMLM-UHFFFAOYSA-N;HMS1609J03;MFCD00225470;NSC123514;AKOS001600193;NSC-123514;AS-50273;CS-0309123;O11679;EN300-1590189;A907277;SR-01000390896;SR-01000390896-1;InChI=1/C12H10N2/c13-14-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8H,13H

Chemical Property of 9H-carbazol-9-amine

Chemical Property:

• Vapor Pressure: 2.88E-06mmHg at 25°C
• Melting Point: 151-152.5℃ (isooctane )
• Boiling Point: 389.3°C at 760 mmHg
• Flash Point: 189.2°C
• PSA: 30.95000
• Density: 1.23g/cm³
• LogP: 3.08950
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 182.084398327
• Heavy Atom Count: 14
• Complexity: 194

Purity/Quality:

98.5% ^*data from raw suppliers

9H-Carbazol-9-amine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3N2N

Technology Process of 9H-carbazol-9-amine

There total 7 articles about 9H-carbazol-9-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

9-nitroso-9H-carbazole (2788-23-0) → 9H-carbazol-9-amine (17223-85-7)

Guidance literature:

With Ti(II)reagent(A); In diethyl ether; for 0.5h; Ambient temperature;

DOI:10.1016/0040-4020(82)80184-1

Reference yield: 62.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9H-carbazol-9-amine (17223-85-7)

Guidance literature:

With potassium hydroxide; In N,N-dimethyl-formamide; at 60 - 65 ℃; for 3h;

Reference yield:

9-nitro-9H-carbazole (31438-20-7) → 9H-carbazol-9-amine (17223-85-7)

Guidance literature:

With ammonium chloride; zinc; In tetrahydrofuran; water; at 0 ℃;

upstream raw materials:

9-nitroso-9H-carbazole

9H-carbazole

diethyl ether

acetic acid

Downstream raw materials:

benzylidene-carbazol-9-yl-amine

salicylaldehyde-carbazol-9-ylimine

1-carbazol-9-yl-3,3-diphenyl-azetidine-2,4-dione

carbazol-9-yl-cinnamyliden-amine

Refernces

• 1、 -. "NEW POLYMERIZABLE LIQUID CRYSTAL HAVING A CARBAZOLE CORE". Page/Page column 12. . Retrieved 2021/01/23.
• 2、 Tonks, Ian A.,Durrell, Alec C.,Gray, Harry B.,Bercaw, John E.. "Groups 5 and 6 terminal hydrazido(2-) complexes: Nβ substituent effects on ligand-to-metal charge-transfer energies and oxidation states". supporting information; experimental part. p. 7301 - 7304. Retrieved 2012/06/16.