Diethylene glycol diacrylate

Base Information

• Chemical Name: Diethylene glycol diacrylate
• CAS No.: 4074-88-8
• Molecular Formula: C10H14O5
• Molecular Weight: 214.218
• Hs Code.: 2916190090
• European Community (EC) Number: 223-791-6
• UN Number: 2810
• UNII: JK01T392JU
• DSSTox Substance ID: DTXSID3025045
• Nikkaji Number: J13.700F
• Wikidata: Q27281543
• ChEMBL ID: CHEMBL1496957
• Mol file: 4074-88-8.mol

Synonyms:DIETHYLENE GLYCOL DIACRYLATE;4074-88-8;Di(ethylene glycol) diacrylate;Oxydiethylene acrylate;Oxydiethylene diacrylate;Acrylic acid, oxydiethylene ester;2-Propenoic acid, oxydi-2,1-ethanediyl ester;TGA 2;diethyleneglycoldiacrylate;2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate;Diacrylate diethylene glycol;Acrylic acid, 2-ethoxyethanol diester;CCRIS 7045;HSDB 4365;EINECS 223-791-6;BRN 1953711;UNII-JK01T392JU;JK01T392JU;DTXSID3025045;2-[2-(prop-2-enoyloxy)ethoxy]ethyl prop-2-enoate;Diethylene Glycol Diacrylate (stabilized with HQ + MEHQ);oxydiethane-2,1-diyl bisacrylate;Diethylene glycol diacrylate(12 cp(25 degrees c));diethyleneglycol diacrylate;SCHEMBL338118;DTXCID705045;CHEMBL1496957;Diethylene glycol diacrylate(degda);Tox21_201088;Acrylate-PEG-acrylate, MW 1,000;Acrylate-PEG-acrylate, MW 2,000;Acrylate-PEG-acrylate, MW 3,400;Acrylate-PEG-acrylate, MW 5,000;LS-111;MFCD00014939;Di(ethylene glycol) diacrylate, 75%;Acrylate-PEG-acrylate, MW 10,000;Acrylate-PEG-acrylate, MW 20,000;AKOS015903217;NCGC00091212-01;NCGC00091212-02;NCGC00091212-03;NCGC00091212-04;NCGC00258640-01;BP-25704;BP-28351;BP-28352;BP-28353;BP-28354;BP-28755;2,2'-oxybis(ethane-2,1-diyl) diacrylate;CAS-4074-88-8;DIETHYLENE GLYCOL DIACRYLATE [HSDB];D5381;FT-0624886;2-(2,2,3-trimethylcyclopent-3-enyl)ethanol;D90390;W-106334;Di(ethylene glycol) diacrylate, technical grade, 75%;Q27281543;2-Propenoic acid, 1,1'-(oxydi-2,1-ethanediyl) ester;28182-75-4

Chemical Property of Diethylene glycol diacrylate

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 0.00201mmHg at 25°C
• Melting Point: >200℃/760mm
• Refractive Index: n20/D 1.463(lit.)
• Boiling Point: 290.905 °C at 760 mmHg
• Flash Point: 124.354 °C
• PSA: 61.83000
• Density: 1.087 g/cm³
• LogP: 0.46140
• Water Solubility.: Slightly soluble in water (1-5g/100ml at 18°C).
• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 10
• Exact Mass: 214.08412354
• Heavy Atom Count: 15
• Complexity: 210
• Transport DOT Label: Poison

Purity/Quality:

98%,99%, ^*data from raw suppliers

DiethyleneGlycolDiacrylate(technicalgrade) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 24-36/38-43
• Safety Statements: 28-39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: C=CC(=O)OCCOCCOC(=O)C=C
• Uses: Diethyleneglycol diacrylate is a cross-linking acrylate monomer for use in coatings, adhesives, and printing plates of prepolymer type. Diethylene glycol diacrylate is used as reactive diluent and cross linking agent of radiation curing system, and also may be used as crosslinking resins, plastics and rubber modifier.

Technology Process of Diethylene glycol diacrylate

There total 5 articles about Diethylene glycol diacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

acryloyl chloride (814-68-6,25189-84-8) + diethylene glycol (111-46-6) → diethyleneglycol(diacrylate) (4074-88-8,26570-48-9)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1055/s-2001-18061

Reference yield:

oxirane (75-21-8,99932-75-9) + acrylic acid (79-10-7) → ethylene glycol diacrylate (2274-11-5,26570-48-9,28158-16-9) + diethyleneglycol(diacrylate) (4074-88-8,26570-48-9)

Guidance literature:

With tempol; 10H-phenothiazine; [Zn₄O(benzene-1,4-dicarboxylate)3]; at 59 ℃; under 7500.75 Torr;

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + diethylene glycol (111-46-6) → diethyleneglycol(diacrylate) (4074-88-8,26570-48-9)

Guidance literature:

With dibutyltin dilaurate; 4-methoxy-phenol; Concentration; Reagent/catalyst; Reflux;

upstream raw materials:

acryloyl chloride

diethylene glycol

oxirane

acrylic acid

Downstream raw materials:

3-[1-(3,4-Dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-propionic acid 2-(2-{3-[1-(3,4-dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-propionyloxy}-ethoxy)-ethyl ester; compound with oxalic acid

1-acryloyloxy-2-[2-(2-thiocyanato-3-phenylpropionyloxy)ethoxy]ethane

acrylic acid 2-[2-(2-thiocyanato-3-p-tolyl-propionyloxy)-ethoxy]-ethyl ester

acrylic acid 2-[2-(2-chloro-3-p-tolyl-propionyloxy)-ethoxy]-ethyl ester

Refernces

• 1、 Xun, Miao-Miao,Xiao, Ya-Ping,Zhang, Ji,Liu, Yan-Hong,Peng, Qi,Guo, Qian,Wu, Wan-Xia,Xu, Yong,Yu, Xiao-Qi. "Low molecular weight PEI-based polycationic gene vectors via Michael addition polymerization with improved serum-tolerance". . p. 45 - 54. Retrieved 2015/04/22.
• 2、 -. "Process for the alkoxylation of organic compounds in the presence of novel framework materials". Page 8. . Retrieved 2008/06/13.