Rhodium(III)acetylacetonate

Base Information

• Chemical Name: Rhodium(III)acetylacetonate
• CAS No.: 14284-92-5
• Molecular Formula: C15H21O6Rh
• Molecular Weight: 400.23
• Hs Code.: 28439000
• Mol file: 14284-92-5.mol

Synonyms:Rhodium(III)acetylacetonate;D82093;Rhodium, tris(2,4-pentanedionato-kO,kO')-, (OC-6-11)-

Chemical Property of Rhodium(III)acetylacetonate

Chemical Property:

• Appearance/Colour: Yellow/orange crystals
• Melting Point: 263-264 °C
• Boiling Point: >280°C
• PSA: 78.90000
• LogP: 2.88030
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 400.03931
• Heavy Atom Count: 22
• Complexity: 314

Purity/Quality:

Rhodium(III) acetylacetonate, 97+% (99.9%-Rh) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-40-63
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Rh+3]
• Uses: Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology. Very effective catalyst for the hydrogenation of carboxylic acids when combined with group 6 or group 7 metal carbonyls.