Trimethyllead acetate

Base Information

• Chemical Name: Trimethyllead acetate
• CAS No.: 5711-19-3
• Molecular Formula: C5H12 O2 Pb
• Molecular Weight: 311.349
• European Community (EC) Number: 227-200-2
• UNII: CC2BHY6YVF
• DSSTox Substance ID: DTXSID80205733
• NSC Number: 102500
• Wikidata: Q83079376
• Mol file: 5711-19-3.mol

Synonyms:trimethyllead acetate

Chemical Property of Trimethyllead acetate

Chemical Property:

• Melting Point: 180 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 26.30000
• Density: g/cm³
• LogP: 1.38440
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 312.06038
• Heavy Atom Count: 8
• Complexity: 93.1

Purity/Quality:

99% ^*data from raw suppliers

ACETOXYTRIMETHYLLEAD(IV) 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,N
• Hazard Codes: T+,N
• Statements: 61-26/27/28-33-50/53-62
• Safety Statements: 53-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O[Pb](C)(C)C

Technology Process of Trimethyllead acetate

There total 1 articles about Trimethyllead acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ trimethyllead acetate (5711-19-3)

Guidance literature:

Tetramethylblei, Quecksilberacetat;

DOI:10.1016/S0022-328X(00)80237-5

Reference yield: 79.0%

ammonium hexafluorophosphate + di-μ-sulphido-tetrakis(triphenylphosphine)-diplatinum(II) + trimethyllead acetate (5711-19-3) → [Pt2(μ-S)2(PPh3)4PbMe3]PF6

Guidance literature:

In methanol; suspn. of Pt and Pb compds. in MeOH stirred at room temp. for 1.5 h; filtered, NH4PF6 added to filtrate, recrystn. by diffusion of Et2O vaporinto CH2Cl2 soln.; elem. anal.;

DOI:10.1016/j.jorganchem.2007.07.010

Reference yield: 51.0%

trimethyllead acetate (5711-19-3) + C9H17N2(1+)*Fe(CO)2(P(OC6H5)3)((C6H5O)2POC6H4)(1-)=[C9H17N2][Fe(CO)2(P(OC6H5)3)((C6H5O)2POC6H4)] (415704-04-0) → Fe(CO)2(P(OC6H5)3)((C6H5O)2POC6H4)(Pb(CH3)3)

Guidance literature:

In tetrahydrofuran; under N2 atm.; mixt. stirred at room temp. for 30-45 min; filtered; filtrate concd.; recrystd. (CH2Cl2-hexane); elem. anal.;

DOI:10.1016/S0020-1693(01)00693-4

Downstream raw materials:

2-acetyl-1,3-oxathiane

2-(trimethylplumbyl)-1,3-oxathiane

Tetramethylblei-(IV)

trans-[Pt(SMe)2(PPh₃)2]