Hexaphenoxycyclotriphosphazene

Base Information

• Chemical Name: Hexaphenoxycyclotriphosphazene
• CAS No.: 1184-10-7
• Deprecated CAS: 1203646-63-2,2236057-00-2,2377320-46-0
• Molecular Formula: C36H30N3O6P3
• Molecular Weight: 693.572
• NSC Number: 117810
• DSSTox Substance ID: DTXSID60152110
• Nikkaji Number: J704.647B
• Wikidata: Q72481818
• Mol file: 1184-10-7.mol

Synonyms:Hexaphenoxycyclotriphosphazene;1184-10-7;PHENOXYCYCLOPOSPHAZENE;2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene;Hexaphenoxycyclotriphosphazatriene;Hexaphenoxy-1,3,5,2,4,6-triazatriphosphorine;Flame Retardant;2,2,4,4,6,6-hexaphenoxy-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine;Phosphaz ene;NSC117810;SCHEMBL419465;DTXSID60152110;Cyclo-tris(diphenoxyphosphonitrile);Trimeric bis(phenoxy)phosphonitrile;MFCD00183774;STK344291;AKOS001604435;CS-W011406;NSC 117810;NSC-117810;AS-17964;H1356;Hexaphenoxy-1,5,2,4,6-triazatriphosphorine;H10907;A927063;AG-690/11351928;2,2,4,4,6,6-Hexaphenoxy-1,3,5,2l5,4l5,6l5-triazatriphosphinine;1,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexahydro-2,2,4,4,6,6-hexaphenoxy-;2,2,4,4,6,6-Hexaphenoxy-2lambda*5*,4lambda*5*,6lambda*5*-[1,3,5,2,4,6]triazatrip;2lambda5,4lambda5,6lambda5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaphenoxy-;2.lambda.5,4.lambda.5,6.lambda.5-1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexaphenoxy-

Chemical Property of Hexaphenoxycyclotriphosphazene

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 116℃
• Boiling Point: 696.518°C at 760 mmHg
• PKA: -12.47±0.50(Predicted)
• Flash Point: 375.041°C
• PSA: 121.89000
• Density: 1.31 g/cm³
• LogP: 10.61940
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: soluble in Toluene
• XLogP3: 11.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 12
• Exact Mass: 693.13474668
• Heavy Atom Count: 48
• Complexity: 912

Purity/Quality:

99% ^*data from raw suppliers

Hexaphenoxycyclotriphosphazene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OP2(=NP(=NP(=N2)(OC3=CC=CC=C3)OC4=CC=CC=C4)(OC5=CC=CC=C5)OC6=CC=CC=C6)OC7=CC=CC=C7
• Uses: Hexaphenoxycyclotriphosphazene is a useful research chemical.

Technology Process of Hexaphenoxycyclotriphosphazene

There total 13 articles about Hexaphenoxycyclotriphosphazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

phenol (108-95-2,27073-41-2) → 2,2,4,4,6,6-hexaphenoxycyclotriphosphazene (1184-10-7)

Guidance literature:

With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; potassium hydroxide; In acetonitrile; at 80 ℃; for 2h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere;

Reference yield: 97.9%

potassium phenolate (100-67-4) + sodium phenoxide (139-02-6) → 2,2,4,4,6,6-hexaphenoxycyclotriphosphazene (1184-10-7)

Guidance literature:

With cesium hydroxide; 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; In 1,2-dichloro-benzene; at 175 ℃; Product distribution / selectivity;

Reference yield: 95.24%

sodium phenoxide (139-02-6) → 2,2,4,4,6,6-hexaphenoxycyclotriphosphazene (1184-10-7)

Guidance literature:

With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; In acetonitrile; at 30 - 80 ℃; for 5h;

upstream raw materials:

sodium phenoxide

2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine

octachlorocyclotetraphosphazene

pentakisphosphorus nitride dichloride

Downstream raw materials:

N-methyl hexa(phenoxy)cyclotriphosphazenium trifluoromethanesulfonate

hexaphenoxycyclotriphosphazene * 2 sulfurtrioxide

hexaphenoxycyclotriphosphazene * 3 sulfurtrioxide

N3P3(OC6H5)5{(η6-OC6H5)Cr(CO)3}

Refernces

• 1、 Kaur, Tejinder,Rajeswararao, Malakalapalli,Ravikanth, Mangalampalli. "Multiporphyrin arrays on cyclotriphosphazene scaffolds". . p. 11051 - 11059. Retrieved 2014.
• 2、 Chattopadhyay, Nitin,Haldar, Basudeb,Mallick, Arabinda,Sengupta, Saumitra. "Photophysical studies on multichromophoric cyclotriphosphazenes. Trinuclear excimer formation in hexakis(2-naphthyloxy)cyclotriphosphazene". . p. 3089 - 3092. Retrieved 2005.
• 3、 Allcock,Best. "". . p. 447,448,449. Retrieved 1964.
• 4、 Wang, Yiqi,Soldatov, Mikhail,Wang, Qingzheng,Liu, Hongzhi. "Phosphazene functionalized silsesquioxane-based porous polymers for absorbing I2, CO2 and dyes". . . Retrieved 2021/03/06.
• 5、 Movahed, Farzaneh Soleymani,Sawant, Dinesh N.,Bagal, Dattatraya B.,Saito, Susumu. "Tris(o-phenylenedioxy)cyclotriphosphazene as a Promoter for the Formation of Amide Bonds between Aromatic Acids and Amines". . p. 3253 - 3262. Retrieved 2020/11/02.