Tricyclo[7.1.0.04,6]decane

Base Information

• Chemical Name: Tricyclo[7.1.0.04,6]decane
• CAS No.: 286-73-7
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.237
• Mol file: 286-73-7.mol

Synonyms:NSC 135450

Chemical Property of Tricyclo[7.1.0.04,6]decane

Chemical Property:

• Vapor Pressure: 0.881mmHg at 25°C
• Boiling Point: 187.1°C at 760 mmHg
• Flash Point: 48.9°C
• PSA: 0.00000
• Density: 0.976g/cm³
• LogP: 2.83260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tricyclo[7.1.0.04,6]decane

There total 3 articles about Tricyclo[7.1.0.04,6]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-tricyclo<7.1.0.04,6>deca-2,7-diene → cyclodecane (293-96-9) + bicyclo<7.1.0>decane (286-76-0,66537-41-5) + trans-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9)

Guidance literature:

With hydrogen; nickel; In hexane; at 60 ℃; for 1h; under 60800 Torr; Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00952847

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + 1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) → cis-Bicyclo<6.1.0>non-4-en (4729-13-9) + trans-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9) + cis-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9)

Guidance literature:

With bis(benzonitrile)palladium(II) dichloride; In dichloromethane; at -10 - 0 ℃; Product distribution; reactants ratio dependence;

DOI:10.1007/BF00995691

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + 1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) → cis-Bicyclo<6.1.0>non-4-en (4729-13-9) + trans-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9) + cis-tricyclo<7.1.0.04,6>decane (286-73-7,89955-58-8,89955-59-9)

Guidance literature:

With bis(benzonitrile)palladium(II) dichloride; In dichloromethane; at -10 - 0 ℃; Product distribution; reactants ratio dependence;

DOI:10.1007/BF00995691

upstream raw materials:

diazomethane

1,5-cis,cis-cyclooctadiene

Refernces

• 1、 Tomilov, Yu. V.,Bordakov, V. G.,Dolgii, I. E.,Nefedov, O. M.. "REACTION OF DIAZOALKANES WITH UNSATURATED COMPOUNDS. COMMUNICATION 2. CYCLOPROPANATION OF OLEFINS BY DIAZOMETHANE IN THE PRESENCE OF PALLADIUM COMPOUNDS". . p. 533 - 538. Retrieved 2007/10/02.