AIDS124927

Base Information

• Chemical Name: AIDS124927
• CAS No.: 3570-93-2
• Molecular Formula: C6H9 N3 O3
• Molecular Weight: 171.156
• Hs Code.: 2928000090
• Mol file: 3570-93-2.mol

Synonyms:1,2,3-Cyclohexanetrione,trioxime (6CI,7CI,8CI,9CI); NSC 56450; Nicon

Chemical Property of AIDS124927

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.5800 (estimate)
• Boiling Point: 343.969°C at 760 mmHg
• Flash Point: 161.827°C
• PSA: 97.77000
• Density: 1.606g/cm³
• LogP: 0.66090

Purity/Quality:

99% ^*data from raw suppliers

1,2,3-CYCLOHEXANETRIONE TRIOXIME 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of AIDS124927

There total 2 articles about AIDS124927 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1,2,3-cyclohexanetrione-1,3-dioxime (10528-54-8) → 1,2,3-cyclohexane trione trioxime (3570-93-2)

Guidance literature:

With hydroxylamine hydrochloride; In methanol; for 5h; Heating;

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 1,2,3-cyclohexane trione trioxime (3570-93-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydrogenchloride / diethyl ether; water / 10 °C

1.2: 4 h / 5 - 25 °C

2.1: hydroxylamine hydrochloride; sodium carbonate / water; ethanol / 25 °C

With hydrogenchloride; hydroxylamine hydrochloride; sodium carbonate; In diethyl ether; ethanol; water;

Reference yield:

1,2,3-cyclohexane trione trioxime (3570-93-2) → 4-hydroxyimino-4,5,6,7-tetrahydro-[2,1,3]benzoxadiazole (57153-55-6)

Guidance literature:

With thionyl chloride; In liquid sulphur dioxide;

DOI:10.1246/bcsj.35.722

upstream raw materials:

1,2,3-cyclohexanetrione-1,3-dioxime

cyclohexanone

Downstream raw materials:

4-hydroxyimino-4,5,6,7-tetrahydro-[2,1,3]benzoxadiazole

Refernces

• 1、 Zsako, J.,Benkoe, A.,Horak, J.,Varhelyi, Cs.. "ACIDITY CONSTANTS OF 1,2,3-CYCLOHEXANE TRIONE DIOXIME (1,3) AND OF 1,2,3-CYCLOHEXANE TRIONE TRIOXIME". . p. 51 - 58. Retrieved 2007/10/02.