Butanol, 4-(trimethylsilyl)-, carbamate

Base Information

• Chemical Name: Butanol, 4-(trimethylsilyl)-, carbamate
• CAS No.: 3121-84-4
• Molecular Formula: C₈H₁₉NO₂Si
• Molecular Weight: 189.33
• DSSTox Substance ID: DTXSID90185138
• Nikkaji Number: J70.071A
• Wikidata: Q83056116
• Mol file: 3121-84-4.mol

Synonyms:Carbamic acid, 4-(trimethylsilyl)butyl ester;4-(Trimethylsilyl)butanol carbamate;BUTANOL, 4-(TRIMETHYLSILYL)-, CARBAMATE;BRN 2411455;3121-84-4;4-(Trimethylsilyl)butyl ester of carbamic acid;C8H19NO2Si;DTXSID90185138;4-(Trimethylsilyl)-1-butanol carbamate;LS-46599

Chemical Property of Butanol, 4-(trimethylsilyl)-, carbamate

Chemical Property:

• Vapor Pressure: 0.00378mmHg at 25°C
• Boiling Point: 280.4°C at 760 mmHg
• Flash Point: 123.4°C
• Density: 0.93g/cm³
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 189.118505383
• Heavy Atom Count: 12
• Complexity: 143

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CCCCOC(=O)N

Technology Process of Butanol, 4-(trimethylsilyl)-, carbamate

There total 2 articles about Butanol, 4-(trimethylsilyl)-, carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-Chlorobutyl)trimethylsilane (1591-24-8) → Carbaminsaeure-(4-trimethylsilyl-butylester) (3121-84-4)

Guidance literature:

Multi-step reaction with 2 steps

1: Li / diethyl ether

2: (i) Py, (ii) liq. NH₃

With lithium; In diethyl ether;

DOI:10.1021/jm00329a012

Reference yield:

4-(trimethylsilyl)-1-butanol (2917-40-0) + phenyl chloroformate (1885-14-9) → Carbaminsaeure-(4-trimethylsilyl-butylester) (3121-84-4)

Guidance literature:

Multistep reaction; (i) Py, (ii) liq. NH₃;

DOI:10.1021/jm00329a012

upstream raw materials:

4-(trimethylsilyl)-1-butanol

phenyl chloroformate

(4-Chlorobutyl)trimethylsilane

Refernces