Bis(3-glycidoxypropyl)tetramethyldisiloxane

Base Information

• Chemical Name: Bis(3-glycidoxypropyl)tetramethyldisiloxane
• CAS No.: 126-80-7
• Deprecated CAS: 909701-29-7,1419318-48-1
• Molecular Formula: C16H34O5Si2
• Molecular Weight: 362.614
• Hs Code.: 2934999090
• European Community (EC) Number: 204-803-9
• NSC Number: 93976
• DSSTox Substance ID: DTXSID80883318
• Nikkaji Number: J184.352D
• Mol file: 126-80-7.mol

Synonyms:126-80-7;Bis(3-glycidoxypropyl)tetramethyldisiloxane;1,3-Bis(3-glycidoxypropyl)tetramethyldisiloxane;1,3-Bis(glycidoxypropyl)tetramethyldisiloxane;NSC93976;[dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silyl]oxy-dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silane;Disiloxane, 1,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-;1,3-BIS(3-GLYCIDYLOXYPROPYL)TETRAMETHYLDISILOXANE;EINECS 204-803-9;NSC 93976;EC 204-803-9;1,3-Bis(3-(2,3-epoxypropoxy)propyl)tetramethyldisiloxane;1,1,3,3-Tetramethyl-1,3-bis(3-glycidyloxypropyl)disiloxane;1,3-Bis(3-glycidoxy propyl)-1,1,3,3-tetraMethyldisiloxane;1,3-Bis(3-(glycidyloxy)propyl)-1,1,3,3-tetramethyldisiloxane;1,3-Bis(3-(2,3-epoxypropoxy)propyl)-1,1,3,3-tetramethyldisiloxane;Disiloxane, 1,1,3,3-tetramethyl-1,3-bis(3-(oxiranylmethoxy)propyl)-;Disiloxane, 1,1,3,3-tetramethyl-1,3-bis(3-(2-oxiranylmethoxy)propyl)-;1,3-Bis[3-(2,3-epoxypropoxy)propyl]tetramethyldisiloxane;1,1,3,3-Tetramethyl-1,3-bis[3-glycidyloxypropyl]disiloxane;1,3-Bis[3-(glycidyloxy)propyl]-1,1,3,3-tetramethyldisiloxane;Disiloxane, 1,1,3,3-tetramethyl-1,3-bis[3-(2-oxiranylmethoxy)propyl]-;Disiloxane, 1,3-bis(3-(2,3-epoxypropoxy)propyl)-1,1,3,3-tetramethyl-;Disiloxane, 1,3-bis[3-(2,3-epoxypropoxy)propyl]-1,1,3,3-tetramethyl-;1,1,3,3-Tetramethyl-1,3-bis(3-(oxiran-2-ylmethoxy)propyl)disiloxane;SCHEMBL329863;1,3-Bis(3-glycidoxypropyl)-1,1,3,3-tetramethyldi;C16H34O5Si2;1,3-bis(3-glycidoxypropyl)-1,1,3,3-tetramethyldisiloxane;DTXSID80883318;C16-H34-O5-Si2;CB2405;MFCD00039672;NSC-93976;AKOS016013018;6,6,8,8-tetramethyl-1,13-bis(oxiran-2-yl)-2,7,12-trioxa-6,8-disilatridecane;Bis (glycidoxypropyl) tetramethyldisiloxane;Oxybis[3-(glycidyloxy)propyldimethylsilane];1,3-epoxypropoxy)propyl]tetramethyldisiloxane;CS-0443665;FT-0631737;S01825;A901420;1,3-Bis[3-(2,3-epoxypropoxy)propyl]tetramethylsiloxane;1,3-Bis(3-(2,3-epoxypropoxy)-propyl)tetramethyldisiloxane;1,1,3,3-tetramethyl-1,3-bis-(3-oxiranylmethoxy-propyl)-disiloxane;1,3-Bis(3-glycidyloxypropyl)tetramethyldisiloxane, >=95.0% (GC);Disiloxane,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-;1,1,3,3-Tetramethyl-1,3-bis[3-(2-oxiranylmethoxy)propyl]disiloxane #;Disiloxane,3-bis[3-(2,3-epoxypropoxy)propyl]-1,1,3,3-tetramethyl-

Chemical Property of Bis(3-glycidoxypropyl)tetramethyldisiloxane

Chemical Property:

• Vapor Pressure: 1.82E-05mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: n20/D 1.452
• Boiling Point: 374.2 °C at 760 mmHg
• Flash Point: 149.1 °C
• PSA: 52.75000
• Density: 1.013 g/cm³
• LogP: 3.02420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 14
• Exact Mass: 362.19447725
• Heavy Atom Count: 23
• Complexity: 319

Purity/Quality:

99.9% ^*data from raw suppliers

1,3-Bis(3-glycidyloxypropyl)tetramethyldisiloxane ≥95.0% (GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(CCCOCC1CO1)O[Si](C)(C)CCCOCC2CO2
• Uses: 1,3-Bis(3-glycidyloxypropyl)tetramethyldisiloxane can be used:As a starting material to synthesize functional poly(siloxane amine)s via an amine-epoxy click polymerization for material and biological applications.To prepare polymer electrolyte membranes (PEM) for fuel cell applications.

Technology Process of Bis(3-glycidoxypropyl)tetramethyldisiloxane

There total 4 articles about Bis(3-glycidoxypropyl)tetramethyldisiloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.7%

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) → glycidyl 1-propenyl ether (1607-23-4) + 1,3-bis(glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane (126-80-7) + 1,1,3,3-tetramethyl-1-(3-(oxiran-2-ylmethoxy)propyl)disiloxane (17980-29-9) + 1-(1-methyl-2-glycidoxyethyl)-1,1,3,3-tetramethyldisiloxane (1567764-85-5)

Guidance literature:

With [{SiO₂}O₂Si(Me)(CH₂)3SBu]2PtCl₂; In toluene; at 80 ℃; for 10h; regioselective reaction;

DOI:10.1134/S107036321801005X

Reference yield:

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) → 1,3-bis(glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane (126-80-7)

Guidance literature:

With platinum;

DOI:10.1021/ja01520a008

Reference yield:

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) → 1,3-bis(glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane (126-80-7) + 1,1,3,3-tetramethyl-1-(3-(oxiran-2-ylmethoxy)propyl)disiloxane (17980-29-9) + 1-(1-methyl-2-glycidoxyethyl)-1,1,3,3-tetramethyldisiloxane (1567764-85-5)

Guidance literature:

With cis-bis(dibenzyl sulfide)Pt(II) dichloride; In dichloromethane; toluene; at 80 - 100 ℃; Sealed tube;

DOI:10.1134/S1070363214010095

upstream raw materials:

Allyl glycidyl ether

1,1,3,3-Tetramethyldisiloxane

Downstream raw materials:

1,3-bis(3-methacryloyloxy-2-hydroxypropoxypropyl)tetramethyldisiloxane

Refernces

• 1、 Almeida, José,Fortunǎ, Maria E.,Pricop, Lucia,Lobiuc, Andrei,Leite, Andreia,Silva, André M.N.,Monteiro, Rodrigo P.,Rangel, Maria,Harabagiu, Valeria,Silva, Ana M.G.. "(Aminophenyl)porphyrins as precursors for the synthesis of porphyrin-modified siloxanes". . p. 1001 - 1012. Retrieved 2019/05/22.
• 2、 Il'Ina,De Vekki,Skvortsov. "Spectral study of interaction between allyl ethers and hydrosiloxanes". . p. 40 - 69. Retrieved 2014/03/21.