(((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi

Base Information

• Chemical Name: (((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi
• CAS No.: 437653-43-5
• Molecular Formula: C₆₉H₇₄N₄NiO
• Molecular Weight: 1034.06
• Mol file: 437653-43-5.mol

Synonyms:(((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi

Chemical Property of (((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi

Chemical Property:

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Technology Process of (((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi

There total 1 articles about (((CH₃)3C)2C₆H₃)3C₂₇H₁₁N₄ONi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

bis(acetylacetonate)nickel(II) + lithium hydroxide monohydrate (1310-66-3) + meso-tris(3,5-di-tert-butylphenyl)-mono-ortho-carbomethoxyphenylporphyrin → (((CH3)3C)2C6H3)3C27H11N4ONi (437653-43-5)

Guidance literature:

With (COCl)2; SnCl₄; In benzene; Ni compd. added to toluene soln. of porphyrin; 24 h at 100°C; evapd.; chromd. (slica gel, CH2Cl2); LiOH*H2O and water added to dioxane soln.; refluxed (24 h); evapd.; toluene added; evapd.; chromd. (silica gel, CH2Cl2-hexane, CH2Cl2-AcOH); evapd.; benzene and (COCl)2 added; stirred (room temp., 2 h); solvent distd.; SnCl4 added; 1 h at room temp.; CH2Cl2 added; aq. NaOH added; org. phase washed (water); dried (Na2SO4); evapd.; chromd.(silica gel, hexane-CH2Cl2); crystd. (CH2Cl2-MeOH); elem. anal.;

DOI:10.1021/ja017531n

upstream raw materials:

lithium hydroxide monohydrate

Refernces