3-Methyl-1-phenyltriazene

Base Information

• Chemical Name: 3-Methyl-1-phenyltriazene
• CAS No.: 16033-21-9
• Molecular Formula: C₇H₉N₃
• Molecular Weight: 135.169
• NSC Number: 136056
• DSSTox Substance ID: DTXSID50166862
• Nikkaji Number: J2.743J
• ChEMBL ID: CHEMBL121569
• Mol file: 16033-21-9.mol

Synonyms:1-methyl-3-phenyl-1-triazene;1-phenyl-3-methyltriazene;3-methyl-1-phenyltriazene

Chemical Property of 3-Methyl-1-phenyltriazene

Chemical Property:

• Vapor Pressure: 0.443mmHg at 25°C
• Refractive Index: 1.5400 (estimate)
• Boiling Point: 194.4°Cat760mmHg
• Flash Point: 71.3°C
• PSA: 36.75000
• Density: 1.04g/cm³
• LogP: 2.29560
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 135.079647300
• Heavy Atom Count: 10
• Complexity: 105

Purity/Quality:

99% ^*data from raw suppliers

3-METHYL-1-PHENYLTRIAZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN=NNC1=CC=CC=C1

Technology Process of 3-Methyl-1-phenyltriazene

There total 6 articles about 3-Methyl-1-phenyltriazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzenediazonium tetrafluoroborate (369-57-3) + methylamine (74-89-5) → 1-phenyl-3-methyltriazene (16033-21-9,20667-79-2,20667-80-5)

Guidance literature:

With sodium carbonate; In N,N-dimethyl-formamide; at -15 ℃;

Reference yield:

N-methyl-N'-phenyl-triazene; copper (I)-salt → 1-methyl-3-phenyltriazene (16033-21-9,20667-79-2,20667-80-5)

Guidance literature:

With sodium sulfide; In not given; decompn. by Na2S;;

Reference yield:

benzenediazonium (2684-02-8) + methylamine (74-89-5) → 1-phenyl-3-methyltriazene (16033-21-9,20667-79-2,20667-80-5) + 1,5-diphenyl-3-methylpentazene (41798-82-7)

Guidance literature:

With sodium carbonate;

upstream raw materials:

benzenediazonium

methylamine

methyl magnesium iodide

Phenyl azide

Downstream raw materials:

N-methylsuccinimide

1-methyl-3-phenyl-triazene-1-carboxylic acid anilide

3-acetyl-3-methyl-1-phenyl-1-triazene

1,5-diphenyl-3-methylpentazene

Refernces

• 1、 Dunn, III, W.J.,Lins, C.,Kumar, G.,Manimaran, T.,Grigoras, S.,et al.. "Substituent Effects on 13C and 15N Chemical Shifts in Triazenes Studied by Principal Components Multivariate Data Analysis". . p. 450 - 456. Retrieved 2007/10/02.