Dichlorobis(cyclopentylamine)platinum

Base Information

• Chemical Name: Dichlorobis(cyclopentylamine)platinum
• CAS No.: 38780-36-8
• Molecular Formula: C₁₀H₂₂Cl₂N₂Pt
• Molecular Weight: 436.284
• European Community (EC) Number: 254-125-2
• UNII: X4G53V7WUH
• DSSTox Substance ID: DTXSID00972273
• Mol file: 38780-36-8.mol

Synonyms:cis-dichlorobis(cyclopentylamine)platinum;dichlorobis(cyclopentylamine)platinum;dichlorobis(cyclopentylamine)platinum, (SP-4-1)-isomer;dichlorobis(cyclopentylamine)platinum, 195Pt-labeled, (SP-4-2)-isomer;NSC 170898

Chemical Property of Dichlorobis(cyclopentylamine)platinum

Chemical Property:

• Vapor Pressure: 24.2mmHg at 25°C
• Boiling Point: 110°C at 760 mmHg
• Flash Point: 17.2°C
• PSA: 52.04000
• LogP: 4.55250
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 435.080798
• Heavy Atom Count: 15
• Complexity: 37.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(C1)N.C1CCC(C1)N.[Cl-].[Cl-].[Pt+2]

Technology Process of Dichlorobis(cyclopentylamine)platinum

There total 5 articles about Dichlorobis(cyclopentylamine)platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

potassium tetrachloroplatinate(II) (10025-99-7) + Cyclopentamine (1003-03-8) → cis-dichloro(cyclopentylamine)platinum (38780-36-8,56846-69-6,176705-99-0)

Guidance literature:

In water; addn. of cyclopentylamine to an aq. soln. of K2PtCl4 and stirring at room temp. for 2 h; filtering off the yellow complex, washing with water, methanol an diethyl ether and drying under vacuum, elem. anal.;

DOI:10.1007/BF00819526

Reference yield:

cis-[diiodobis(cyclopentylamino)platinum(II)] (71360-93-5,850940-74-8) + potassium chloride → cis-dichloro(cyclopentylamine)platinum (38780-36-8,56846-69-6,176705-99-0)

Guidance literature:

In not given; an adapted version of Dhara's method (Indian J. Chem. 8 (1970) 193); diaqua species obtained from Pt complex, reacted with KCl; ppt. washed (H2O), dried;

DOI:10.1016/j.ica.2004.12.030

Reference yield:

Cyclopentamine (1003-03-8) → cis-dichloro(cyclopentylamine)platinum (38780-36-8,56846-69-6,176705-99-0)

Guidance literature:

Multi-step reaction with 2 steps

1: water / 0.67 h / 20 °C

2: silver nitrate / water / 24 h / 50 °C

With silver nitrate; In water;

DOI:10.1039/c2dt32360e

upstream raw materials:

cis-[diiodobis(cyclopentylamino)platinum(II)]

potassium tetrachloroplatinate(II)

Cyclopentamine

trans-[diiodobis(cyclopentylamino)platinum(II)]

Downstream raw materials:

trans-{Pt(cyclopentylNH₂)2Cl₂}

C₁₀H₂₄Cl₂N₂O₂Pt

Refernces

• 1、 Rochon, Fernande D.,Buculei, Viorel. "Study of Pt(II)-cyclic amines complexes of the types cis- and trans-Pt(amine)2I2 and cis- and trans-Pt(amine) 2(NO3)2 and their aqueous products". . p. 2040 - 2056. Retrieved 2008/10/09.