Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester

Base Information

• Chemical Name: Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester
• CAS No.: 130534-80-4
• Molecular Formula: C₁₉H₂₇FO₂S
• Molecular Weight: 338.487
• Mol file: 130534-80-4.mol

Synonyms:Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester

Chemical Property of Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester

Chemical Property:

Purity/Quality:

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Technology Process of Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester

There total 1 articles about Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.1%

cyclododecanol (1724-39-6) + 4-fluorophenyl chlorothionoformate (42908-73-6) → Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester (130534-80-4)

Guidance literature:

With pyridine; In dichloromethane;

DOI:10.1016/S0040-4020(01)90359-X

Reference yield: 98.0%

Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester (130534-80-4) → cyclododecane (294-62-2)

Guidance literature:

With tris-(trimethylsilyl)silane; triethyl borane; oxygen; In benzene; at 25 ℃; for 0.166667h; other reagent: diphenylsilane;

DOI:10.1016/S0040-4039(00)97705-0

Reference yield:

diphenylsilane (775-12-2) + Thiocarbonic acid O-cyclododecyl ester O-(4-fluoro-phenyl) ester (130534-80-4) → cyclododecane (294-62-2) + C19H15FO2SSi

Guidance literature:

With air; triethyl borane; In ⁽²⁾H₈-toluene; at -30 - -20 ℃;

DOI:10.1016/S0040-4020(01)86502-9

upstream raw materials:

cyclododecanol

4-fluorophenyl chlorothionoformate

Downstream raw materials:

cyclododecane

Refernces

• 1、 Barton,Dorchak,Jaszberenyi. "The invention of radical reactions. Part XXIV. Relative rates of acylation and radical deoxygenation of secondary alcohols". . p. 7435 - 7446. Retrieved 2007/10/02.