2-(Diethylamino)ethyl methacrylate

Base Information

• Chemical Name: 2-(Diethylamino)ethyl methacrylate
• CAS No.: 105-16-8
• Deprecated CAS: 138164-47-3,151768-83-1,168066-58-8,76398-99-7,1453489-91-2,474094-70-7,1432143-61-7,151768-83-1,168066-58-8,76398-99-7
• Molecular Formula: C10H19NO2
• Molecular Weight: 185.266
• Hs Code.: 29224999
• European Community (EC) Number: 203-275-7
• NSC Number: 14490
• UN Number: 1993
• UNII: N5SI2E7HOU
• DSSTox Substance ID: DTXSID4026713
• Nikkaji Number: J107.836D
• Wikidata: Q27284584
• NCI Thesaurus Code: C77544
• ChEMBL ID: CHEMBL3182085
• Mol file: 105-16-8.mol

Synonyms:2-(diethylamino)ethyl methacrylate;DEAEM cpd;diethylaminoethyl methacrylate;Et2NH-ethyl methacrylate;N,N-diethylaminoethyl methacrylate;N,N-diethylaminoethyl methacrylate acetate;N,N-diethylaminoethyl methacrylate hydrochloride

Chemical Property of 2-(Diethylamino)ethyl methacrylate

Chemical Property:

• Appearance/Colour: clear light colored liquid
• Vapor Pressure: 0.111mmHg at 25°C
• Melting Point: -60 °C
• Refractive Index: n20/D 1.444(lit.)
• Boiling Point: 239.327 °C at 760 mmHg
• PKA: 9.18±0.25(Predicted)
• Flash Point: 80.975 °C
• PSA: 29.54000
• Density: 0.93 g/cm³
• LogP: 1.44750
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 7
• Exact Mass: 185.141578849
• Heavy Atom Count: 13
• Complexity: 174
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

2-(Diethylamino)ethyl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20-36/38-43
• Safety Statements: 26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: CCN(CC)CCOC(=O)C(=C)C
• Uses: 2-(Diethylamino)ethyl Methacrylate is used in preparation method and application of Hydrogel assembled self-adhesive material.

Technology Process of 2-(Diethylamino)ethyl methacrylate

There total 2 articles about 2-(Diethylamino)ethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.1%

methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) + 2-(Diethylamino)ethanol (100-37-8) → 2-(diethylamino)ethyl methacrylate (105-16-8,25119-82-8)

Guidance literature:

With 10H-phenothiazine; lithium hydroxide; In hexane; at 65 - 73 ℃; for 5h; Reagent/catalyst;

Reference yield:

→ 2-(diethylamino)ethyl methacrylate (105-16-8,25119-82-8)

Guidance literature:

Methyl-methacrylat, entspr. Alkohol;

Reference yield: 100.0%

2-(diethylamino)ethyl methacrylate (105-16-8,25119-82-8) + C14H17BrO5 → C24H36NO7(1+)*Br(1-)

Guidance literature:

With hydroquinone; In acetonitrile; at 70 ℃; for 10h;

upstream raw materials:

methacrylic acid methyl ester

2-(Diethylamino)ethanol

Downstream raw materials:

N,N,N-triethyl-N-[2-(methacryloyloxy)ethyl]ammonium iodide

benzyldiethyl{2-[(2-methyl-1-oxoallyl)oxy]ethyl}ammonium chloride

Refernces

• 1、 -. "Improved preparation method of dialkylaminoethyl methacrylate". Paragraph 0020; 0021; 0022; 0023; 0024-0028; 0035-0043. . Retrieved 2017/08/29.
• 2、 -. "Multi-purpose polymers, methods and compositions". . . Retrieved 2008/06/13.