Dimethylamine dimethyldithiocarbamate

Base Information

• Chemical Name: Dimethylamine dimethyldithiocarbamate
• CAS No.: 598-64-1
• Molecular Formula: C5H12N2S2
• Molecular Weight: 166.312
• Hs Code.: 2930909090
• NSC Number: 100885,6205
• UNII: 83515OR55B
• Wikidata: Q27269398
• ChEMBL ID: CHEMBL3185962
• Mol file: 598-64-1.mol

Synonyms:NSC-6205;NSC-100885;WLN: SUYSHN1&1 &1M1;Carbamic acid, dimethylamine salt (1:1);CHEMBL3185962;NSC6205;Dimethylamine dimethylcarbamodithioate;MFCD00067267;NSC100885;AKOS003375146;Dimethyldithiocarbamicaciddimethylammoniumsalt;CS-0454143;D89709;Q27269398;N,N-DIMETHYLDITHIOCARBAMIC ACID DIMETHYLAMMONIUM SALT

Chemical Property of Dimethylamine dimethyldithiocarbamate

Chemical Property:

• Vapor Pressure: 10.2mmHg at 25°C
• Melting Point: 132°C
• Refractive Index: 1.5300 (estimate)
• Boiling Point: 129.4°Cat760mmHg
• Flash Point: 32°C
• PSA: 86.16000
• Density: 1.161g/cm³
• LogP: 0.98920
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 166.05984080
• Heavy Atom Count: 9
• Complexity: 62.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dimethylammonium Dimethyldithiocarbamate >95.0%(T) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CNC.CN(C)C(=S)S

Technology Process of Dimethylamine dimethyldithiocarbamate

There total 4 articles about Dimethylamine dimethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Thiram (137-26-8,93196-73-7) + dimethyl amine (124-40-3) → S-(N,N-dimethylthiocarbamoyl)-N,N-dimethylthiohydroxylamine (2801-22-1) + dimethylammonium dimethyldithiocarbamate (598-64-1)

Guidance literature:

In water; at 20 ℃; for 3h;

DOI:10.1007/BF02498275

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + dimethyl amine (124-40-3) → dimethylammonium dimethyldithiocarbamate (598-64-1)

Guidance literature:

In N,N-dimethyl-formamide; at 25 ℃; Thermodynamic data; enthalpy of reaction = -92.4 kJ*mol^-1;

DOI:10.1006/jcht.1995.0146

Reference yield:

dimethyl amine (124-40-3) → dimethylammonium dimethyldithiocarbamate (598-64-1)

Guidance literature:

With water;

upstream raw materials:

carbon disulfide

dimethyl amine

Thiram

Downstream raw materials:

Thiram

N,N-dimethylbenzenesulfonamide

Benzenesulfinic acid

N,N-dimethyl-4-chlorobenzamide

Refernces

• 1、 Aryanasab, Fezzeh,Shabanian, Meisam. "A catalyst-free 1,4-Michael-type reaction of in situ generated ortho-quinone methides (o-QMs) with dithiocarbamic acid salts in water". . p. 1703 - 1713. Retrieved 2019/04/17.
• 2、 Boi, Luu Van. "Thiocarbamoylation of amine-containing compounds 5. The mechanism of reactions of tetramethylthiuram disulfide with aliphatic amines". . p. 335 - 343. Retrieved 2007/10/03.