Aniline monoanion

Base Information

• Chemical Name: Aniline monoanion
• CAS No.: 27547-14-4
• Molecular Formula: C₆H₆N
• Molecular Weight: 92.1203
• Mol file: 27547-14-4.mol

Synonyms:Aniline monoanion

Chemical Property of Aniline monoanion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Aniline monoanion

There total 10 articles about Aniline monoanion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

aniline (62-53-3) → Aniline monoanion (27547-14-4)

Guidance literature:

With potassium hydride; cryptand 222B; In tetrahydrofuran; for 0.333333h;

DOI:10.1016/0040-4020(80)80011-1

Reference yield:

acetaldehyde enolate (64723-93-9) + aniline (62-53-3) → Aniline monoanion (27547-14-4) + acetaldehyde (75-07-0,9002-91-9)

Guidance literature:

at 100 - 670 ℃; under 0.8 - 2.4 Torr; Thermodynamic data; intrinsic gas phase acidity (acid dissociation energy) is measured as a model for strong interactions in proteins and enzymes;

DOI:10.1021/ja00218a013

Reference yield:

pyridine (110-86-1) + N,P,P-triphenylphosphinic amide (6190-28-9) → C17H15NOP(1+) (1004853-94-4) + Aniline monoanion (27547-14-4)

Guidance literature:

In dimethyl sulfoxide; at 85 ℃; Kinetics;

DOI:10.1002/poc.1788

upstream raw materials:

acetaldehyde enolate

aniline

pyridine

N,P,P-triphenylphosphinic amide

Downstream raw materials:

C₃H₆P^(1-)

aniline

Refernces

• 1、 Guha, Arun Kanti,Kim, Chan Kyung,Lee, Hai Whang. "Kinetics and mechanism of the pyridinolysis of N-aryl-P,P-diphenyl phosphinic amides in dimethyl sulfoxide". . p. 474 - 479. Retrieved 2012/02/04.
• 2、 Le Goaller,Pasquini,Pierre. "EFFETS DE CRYPTANDS ET ACTIVATION DE BASES-IV. ACTION DES HYDRURES ALCALINS SUR LES ACIDES FAIBLES. GENESE DE PHENATES, ALCOOLATES, AMIDURES ET CARBANIONS DANS LE THF ET LE BENZENE.". . p. 237 - 243. Retrieved 2007/10/02.