Uranium, bis(acetato)dioxo-, dihydrate

Base Information

• Chemical Name: Uranium, bis(acetato)dioxo-, dihydrate
• CAS No.: 6159-44-0
• Molecular Formula: C₄H₁₀O₈U
• Molecular Weight: 424.147
• Hs Code.: 28441000
• Mol file: 6159-44-0.mol

Synonyms:Uranium, bis(acetato)dioxo-, dihydrate;acetic acid;dioxouranium;dihydrate;Bis(aceto)dioxouranium dihydrate;Bis(aceto-O)dioxouranium dihydrate;Uranium acetate,dihydrate;UNII-KJF3TEU4G6;CCRIS 9302;1-(acetoxydioxouraniooxy)ethanone dihydrate

Chemical Property of Uranium, bis(acetato)dioxo-, dihydrate

Chemical Property:

• PSA: 132.86000
• Density: 2.890
• LogP: -2.85380
• Storage Temp.: Store at RT.
• Water Solubility.: soluble in 10 parts H2O; slightly soluble alcohol [MER06]
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 426.10400
• Heavy Atom Count: 13
• Complexity: 129

Purity/Quality:

98%,99%, ^*data from raw suppliers

URANIUM OXYACETATE DIHYDRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,R,N
• Hazard Codes: T+,R,N
• Statements: 26/28-33-51/53
• Safety Statements: 20/21-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)O.CC(=O)O.O.O.O=[U]=O

Technology Process of Uranium, bis(acetato)dioxo-, dihydrate

There total 1 articles about Uranium, bis(acetato)dioxo-, dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

uranyl(VI) perchlorate + water (7732-18-5) + sodium acetate (127-09-3) + acetic acid (64-19-7,77671-22-8) → uranyl acetate dihydrate (57286-07-4,34788-61-9,6159-44-0,202833-02-1,86028-86-6,32627-97-7)

Guidance literature:

With perchloric acid; In water; aq. soln. of UO2(ClO4)2 (18.94 mM), HClO4 (18.94 mM) and acetic acid/Na acetate buffer; not isolated, detected by EXAFS;

DOI:10.1039/b106642k

Reference yield: 65.0%

uranyl acetate dihydrate (57286-07-4,34788-61-9,6159-44-0,202833-02-1,86028-86-6,32627-97-7) + salicylaldehyde (90-02-8) + anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 2H(1+)*2UO2(2+)*3C6H4(CO2)NCHC6H4O(2-)=H2{(UO2)2(C6H4(CO2)NCHC6H4O)3}

Guidance literature:

In ethanol; separate dissolving of salicylaldehyde (2 mmol), anthranilic acid (2 mmol) and (UO2(CH3COO)2(H2O)2) (2 mmol) in ethanol; mixing together; refluxing for 30 min; pptn.; washing with water, ethanol, ether; drying in vac. over concd. H2SO4; elem. anal.;

Reference yield:

uranyl acetate dihydrate (57286-07-4,34788-61-9,6159-44-0,202833-02-1,86028-86-6,32627-97-7) + N,N-diphenylthiourea (102-08-9) → UO2(CH3COO)2*C6H5NHCSNHC6H5 (99589-25-0)

Guidance literature:

In solid; UO2Ac2*2H2O and ligand were well mixed (molar ratio varying from 1:1 to 1:6) and heated in an oven at 100°C for a few minutes;;

DOI:10.1016/0040-6031(85)87080-5

upstream raw materials:

water

sodium acetate

acetic acid

Downstream raw materials:

UO₂(C₉H₅N(O)CHN-o-C₆H₄CH₃)2

UO₂(CH₃COO)2*C₆H₅NHCSNHC₆H₅

UO₂(C₉H₅N(O)CHNC₆H₅)2

UO₂(C₉H₅N(O)CHN-o-C₆H₄OH)(AcO)

Refernces