diphenylphosphaneylmethanethiol borane complex

Base Information

• Chemical Name: diphenylphosphaneylmethanethiol borane complex
• CAS No.: 613688-05-4
• Molecular Formula: C₁₃H₁₆BPS
• Molecular Weight: 246.121
• Mol file: 613688-05-4.mol

Synonyms:diphenylphosphaneylmethanethiol borane complex

Chemical Property of diphenylphosphaneylmethanethiol borane complex

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of diphenylphosphaneylmethanethiol borane complex

There total 12 articles about diphenylphosphaneylmethanethiol borane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(borane)diphenylphosphinomethanethiol acetate (446822-71-5) → diphenylphosphaneylmethanethiol borane complex (613688-05-4)

Guidance literature:

With sodium hydroxide; In methanol; at 20 ℃; for 3h;

DOI:10.1039/d0cc05395c

Reference yield: 51.0%

dimethylsulfide borane complex (13292-87-0) + diphenyl(α-sulfanylmethyl)phosphine oxide (51649-25-3) → diphenylphosphaneylmethanethiol borane complex (613688-05-4)

Guidance literature:

dimethylsulfide borane complex; diphenyl(α-sulfanylmethyl)phosphine oxide; In toluene; at 60 ℃; for 16h; Inert atmosphere; Schlenk technique;

dimethylsulfide borane complex; In ethyl acetate; for 0.166667h; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.1055/s-0036-1591546

Reference yield: 29.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + dimethylsulfide borane complex (13292-87-0) + diphenyl(α-sulfanylmethyl)phosphine oxide (51649-25-3) → C17H24BOPS + diphenylphosphaneylmethanethiol borane complex (613688-05-4)

Guidance literature:

at 60 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1055/s-0036-1591546

upstream raw materials:

(borane)diphenylphosphinomethanethiol acetate

hydroxymethyl(diphenyl)phosphine borane complex

(borane)diphenylphosphinomethyl sulfonate

diphenylphosphane

Downstream raw materials:

N₃(CH₂)5C(O)SCH₂P(C₆H₅)2BH₃

2-tert-butoxycarbonylamino-3-[(diphenylphosphanyl)-methylsulfanylcarbonyl]-propionic acid benzyl ester

Refernces

• 1、 Sowa, Sylwia,Stankevi?, Marek,Flis, Anna,Pietrusiewicz, K. Micha?. "Reduction of Tertiary Phosphine Oxides by BH 3 Assisted by Neighboring Activating Groups". . p. 2106 - 2118. Retrieved 2018/02/28.
• 2、 Carroll, Laurence,Boldon, Sophie,Bejot, Romain,Moore, Jane E.,Declerck, Jerome,Gouverneur, Veronique. "The traceless Staudinger ligation for indirect 18F- radiolabelling". . p. 136 - 140. Retrieved 2011/02/23.