Allylpalladiumchloridedimer

Base Information

• Chemical Name: Allylpalladiumchloridedimer
• CAS No.: 12012-95-2
• Molecular Formula: C6H10Cl2Pd2
• Molecular Weight: 365.89
• Hs Code.: 28439090
• Mol file: 12012-95-2.mol

Synonyms:Allylchloropalladium dimer;ALLYLPALLADIUMCHLORIDEDIMER;PENAXHPKEVTBLF-UHFFFAOYSA-L;Allylpalladium (II) chloride dimer;Di-mu-chlorobis[(eta-allyl)palladium(II)];FT-0622053

Chemical Property of Allylpalladiumchloridedimer

Chemical Property:

• Appearance/Colour: yellow powder
• Vapor Pressure: 8480mmHg at 25°C
• Melting Point: 120°C (dec.)
• PSA: 0.00000
• LogP: 3.65900
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 365.82333
• Heavy Atom Count: 10
• Complexity: 6.8

Purity/Quality:

99% ^*data from raw suppliers

Allylpalladium(II) Chloride Dimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,Xn
• Statements: 36/37/38-40
• Safety Statements: 26-36-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [CH2-]C=C.[CH2-]C=C.Cl[Pd+].Cl[Pd+]
• Uses: Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry. [Pd(allyl)Cl]2 can be used as a catalyst: For the silylation of organobromides. To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides. To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization. Application Guide for Palladium Catalyzed Cross-Coupling Reactions ChemDose: Convenient Dosing of Catalysts and Reagents