Magnesium iodide (MgI)

Base Information

• Chemical Name: Magnesium iodide (MgI)
• CAS No.: 10377-58-9
• Molecular Formula: I₂Mg
• Molecular Weight: 278.114
• UNII: W74QE3H320
• Nikkaji Number: J43.881B
• Wikidata: Q416265
• Mol file: 10377-58-9.mol

Synonyms:Magnesium iodide (MgI);MAGNESIUM IODIDE [MI];MAGNESIUM IODIDE ANHYDROUS;BLQJIBCZHWBKSL-UHFFFAOYSA-L;MAGNESIUM IODIDE [WHO-DD];AKOS025293999;Q416265;J-001038;Magnesium iodide, ~10 mesh beads, trace metals grade, 99.99% purity ampoules

Chemical Property of Magnesium iodide (MgI)

Chemical Property:

• Appearance/Colour: white crystalline solid
• Melting Point: 637 °C (dec.)(lit.)
• PSA: 0.00000
• Density: 4.43 g/mL at 25 °C(lit.)
• LogP: 1.77140
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 277.79399
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): T,Xi
• Hazard Codes: T,Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Mg+2].[I-].[I-]
• Use Description: Magnesium iodide, a specific chemical compound, serves varied purposes across different fields. In the field of organic synthesis, it acts as a Lewis acid catalyst, facilitating a range of reactions such as Friedel-Crafts reactions and Grignard reactions, enabling the formation of complex organic molecules for research and industrial applications. In the pharmaceutical industry, it may serve as a reactant or reagent in the synthesis of specific drug intermediates. Additionally, in the field of material science, magnesium iodide can be utilized as a precursor for the production of magnesium-based compounds with diverse properties. Its applications in organic synthesis, pharmaceuticals, and materials science underscore its importance in driving innovation, scientific research, and practical solutions across these distinct domains.

Technology Process of Magnesium iodide (MgI)

There total 45 articles about Magnesium iodide (MgI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sulfuric acid (7664-93-9) + hydrogen iodide (10034-85-2) + magnesium oxide → magnesium sulfate (7487-88-9) + magnesium iodide (10377-58-9)

Guidance literature:

70 °C; 1-2. step of Mg-S-I water splitting cycle;

DOI:10.1246/cl.1983.679

Reference yield: 73.0%

[(IP-)2Al]2(μ2η3-OCO2) + tetra-(n-butyl)ammonium iodide (311-28-4) + magnesium (7439-95-4) → Bu4N[(IP(-))2Al] + magnesium iodide (10377-58-9) + magnesium carbonate

Guidance literature:

[(IP-)2Al]2(μ2η3-OCO2); magnesium; In tetrahydrofuran; at 60 ℃; for 12h; Inert atmosphere;

tetra-(n-butyl)ammonium iodide; In diethyl ether; for 24h; Inert atmosphere;

DOI:10.1039/c2cc37208h

Reference yield: 65.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + magnesium (7439-95-4) → magnesium iodide (10377-58-9)

Guidance literature:

In diethyl ether; Inert atmosphere; Darkness;

DOI:10.1039/d0gc04268d

upstream raw materials:

iodine

strontium(II) oxide

sulfur dioxide

magnesium chloride

Downstream raw materials:

magnesium fluoride

Refernces

• 1、 Arkhireeva, T. M.,Bulychev, B. M.,Sokolova, T. A.,Soloveichik, G. L.,Belsky, V. K.,Boika, G. N.. "". . p. 221 - 226. Retrieved 1988.
• 2、 Shiga, Tohru,Hase, Yoko,Kato, Yuichi,Inoue, Masae,Takechi, Kensuke. "A rechargeable non-aqueous Mg-O2 battery". . p. 9152 - 9154. Retrieved 2013.
• 3、 Mar, Gerd N. La,Ropp, Jeffrey S. de,Latos-Grazynski, Lechoslaw,Balch, Alan L.,Johnson, R. B.,et al.. "Proton NMR Characterization of the Ferryl Group in the Model Heme Complexes and Hemoproteins: Evidence for the FeIV=O Group in Ferryl Myoglobin and Compound II of Horseradish Peroxidase". . p. 782 - 787. Retrieved 1983.
• 4、 Emeleus, H. J.,Haszeldine, R. N.. "". . . Retrieved 1949.
• 5、 Bergstrom, F. W.. "". . p. 2848 - 2848. Retrieved 1926.
• 6、 Nicolaou,Yu, Ruocheng,Lu, Zhaoyong,Alvarez, Fernando G.. "Total Synthesis of Gukulenin B via Sequential Tropolone Functionalizations". supporting information. p. 5190 - 5196. Retrieved 2022/03/27.
• 7、 Eyselein, Jonathan,F?rber, Christian,Grams, Samuel,Harder, Sjoerd,Knüpfer, Christian,Langer, Jens,Martin, Johannes,Thum, Katharina,Wiesinger, Michael. "Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings". supporting information. p. 9102 - 9112. Retrieved 2020/03/30.