3,3-Dimethyl-1-p-tolyltriazene

Base Information

• Chemical Name: 3,3-Dimethyl-1-p-tolyltriazene
• CAS No.: 7203-89-6
• Molecular Formula: C9H13 N3
• Molecular Weight: 163.222
• European Community (EC) Number: 633-237-9
• NSC Number: 48821
• UNII: 2E2JG4C5BD
• DSSTox Substance ID: DTXSID801032012
• Nikkaji Number: J36.531I
• ChEMBL ID: CHEMBL3230455
• Mol file: 7203-89-6.mol

Synonyms:1-(4-tolyl)-3,3-dimethyltriazene;1-p-tolyl-3,3-dimethyltriazene

Chemical Property of 3,3-Dimethyl-1-p-tolyltriazene

Chemical Property:

• Vapor Pressure: 0.0629mmHg at 25°C
• Melting Point: 49-51 °C(lit.)
• Boiling Point: 231.3°C at 760 mmHg
• Flash Point: 93.7°C
• PSA: 27.96000
• Density: 0.98g/cm³
• LogP: 2.55530
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 163.110947427
• Heavy Atom Count: 12
• Complexity: 146

Purity/Quality:

99% ^*data from raw suppliers

3,3-DIMETHYL-1-P-TOLYLTRIAZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-40
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N=NN(C)C

Technology Process of 3,3-Dimethyl-1-p-tolyltriazene

There total 3 articles about 3,3-Dimethyl-1-p-tolyltriazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-toluidine (106-49-0,12221-03-3) + dimethyl amine (124-40-3) → 3,3-dimethyl-1-(p-tolyl)-1-triazene (7203-89-6)

Guidance literature:

p-toluidine; With hydrogenchloride; sodium nitrite; at 0 - 10 ℃;

dimethyl amine; With sodium carbonate; In water; for 0.5h; cooling;

Reference yield:

p-methylbenzenediazonium chloride (2028-84-4) + dimethyl amine (124-40-3) → 3,3-dimethyl-1-(p-tolyl)-1-triazene (7203-89-6)

Guidance literature:

Reference yield:

→ 3,3-dimethyl-1-(p-tolyl)-1-triazene (7203-89-6)

Guidance literature:

DOI:10.1016/S0040-4020(01)92598-0

upstream raw materials:

p-methylbenzenediazonium chloride

dimethyl amine

p-toluidine

Downstream raw materials:

4-chloro-4'-methylbiphenyl

C₁₇H₁₈ClNO₄S₂

1-((Z)-4-Chloro-2-methyl-but-2-ene-1-sulfonyl)-4-methyl-benzene

N-methyl-1-(m-tolyl)methanamine

Refernces

• 1、 Wang, Fengze,Wang, Chen,Sun, Guoping,Zou, Gang. "Highly efficient palladium-catalyzed cross-coupling of diarylborinic acids with arenediazoniums for practical diaryl synthesis". supporting information. . Retrieved 2019/12/25.
• 2、 Manolov, Ilia,Machulla,Momekov. "Synthesis, physicochemical characterization and preliminary pharmacological in vitro evaluation of two novel cytotoxic benzophenone-linked 3,3-dimethyltriazenes". . p. 511 - 516. Retrieved 2007/10/03.