5-Acetylbenzo[c]phenanthrene

Base Information

• Chemical Name: 5-Acetylbenzo[c]phenanthrene
• CAS No.: 63018-98-4
• Molecular Formula: C20H14O
• Molecular Weight: 270.34
• Mol file: 63018-98-4.mol

Synonyms:2-Acetyl-3:4-benzphenanthrene;5-acetylbenzo[c]phenanthrene;1-Benzo[c]phenanthren-5-yl-aethanon;1-benzo[c]phenanthren-5-yl-ethanone;BENZO(c)PHENANTHRENE,5-ACETYL;

Chemical Property of 5-Acetylbenzo[c]phenanthrene

Chemical Property:

• Vapor Pressure: 5.38E-10mmHg at 25°C
• Refractive Index: 1.6700 (estimate)
• Boiling Point: 496.5°C at 760 mmHg
• Flash Point: 222.1°C
• PSA: 17.07000
• Density: 1.21g/cm³
• LogP: 5.34880

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-Acetylbenzo[c]phenanthrene

There total 4 articles about 5-Acetylbenzo[c]phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

benzo[c]phenathrene (195-19-7) + acetyl chloride (75-36-5) → 5-acetylbenzo[c]phenanthrene (63018-98-4)

Guidance literature:

With aluminium trichloride; In dichloromethane; for 3h; Ambient temperature;

DOI:10.1039/a607258e

Reference yield:

benzo[c]phenathrene (195-19-7) + acetic anhydride (108-24-7) → 5-acetylbenzo[c]phenanthrene (63018-98-4)

Guidance literature:

With aluminium trichloride; chlorobenzene;

DOI:10.1021/jo01155a006

Reference yield:

methyl magnesium iodide (917-64-6) → 5-acetylbenzo[c]phenanthrene (63018-98-4)

Guidance literature:

With diethyl ether; Erhitzen des vom Aether befreiten Reaktionsgemisches in Benzol auf Siedetemperatur und Erhitzen des nach der Hydrolyse erhaltenen Reaktionsprodukts mit Essigsaeure und konz. wss. Salzsaeure auf dem Dampfbad;

DOI:10.1039/jr9400001159

upstream raw materials:

benzo[c]phenathrene

acetic anhydride

acetyl chloride

aluminium trichloride

Refernces

• 1、 Sarobe, Martin,Jenneskens, Leonardus W.,Wesseling, Jolanda,Wiersum, Ulfert E.. "High temperature gas phase syntheses of C20H12 cyclopenta-fused polycyclic aromatic hydrocarbons: Benz[l]acephenanthrylene and benz[j]acephenanthrylene and their selective rearrangement to benzo[j]fluoranthene". . p. 703 - 708. Retrieved 2007/10/03.