Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃

Base Information

• Chemical Name: Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃
• CAS No.: 1152315-29-1
• Molecular Formula: C₂₈H₂₉NOSiZr
• Molecular Weight: 514.854
• Mol file: 1152315-29-1.mol

Synonyms:Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃

Chemical Property of Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃

Chemical Property:

Purity/Quality:

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Technology Process of Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃

There total 1 articles about Zr(C₅H₄)2Si(CH₃)2CHC₆H₅CHCHNC₆H₄OCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

dimethylsilylenebiscyclopentadienylzirconium dichloride (86050-32-0) + N-cinnamylidene-p-anisidine (80542-40-1) → Zr(C5H4)2Si(CH3)2CHC6H5CHCHNC6H4OCH3 (1152315-29-1)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; (Ar); dropwise addn. of a soln. of Li compd. in hexanes to a soln. of Zrcomplex in THF at -78°C, stirring for 1 h, addn. of a soln. of l igand in THF, slow warming to room temp. within 5 h, stirring for 1 h; evapn. in vac., addn. of toluene, filtration under Ar, evapn. in vac., recrystn. (toluene/pentane); elem. anal.;

DOI:10.1021/om900142c

Reference yield: 88.0%

benzophenone (119-61-9) + Zr(C5H4)2Si(CH3)2CHC6H5CHCHNC6H4OCH3 (1152315-29-1) → Zr(C5H4)2Si(CH3)2OC(C6H5)2CHC6H5CHCHNC6H4OCH3 (1152315-39-3)

Guidance literature:

In toluene; (Ar); addn. of ketone to a soln. of of Zr complex in toluene, stirring at 80°C for 8 h, cooling to room temp.; passing through Celite under Ar, evapn. in vac., recrystn. (toluene/pentane); elem. anal.;

DOI:10.1021/om900142c

upstream raw materials:

dimethylsilylenebiscyclopentadienylzirconium dichloride

N-cinnamylidene-p-anisidine

Downstream raw materials:

Zr(C₅H₄)2Si(CH₃)2OC(C₆H₅)2CHC₆H₅CHCHNC₆H₄OCH₃

Refernces