Ethylene glycol butyl vinyl ether

Base Information

• Chemical Name: Ethylene glycol butyl vinyl ether
• CAS No.: 4223-11-4
• Molecular Formula: C8H16 O2
• Molecular Weight: 144.214
• Hs Code.: 2909199090
• European Community (EC) Number: 224-172-3
• NSC Number: 32633
• UNII: 5AK3IYE5IJ
• DSSTox Substance ID: DTXSID30195054
• Nikkaji Number: J34.805H
• Wikidata: Q83067926
• Mol file: 4223-11-4.mol

Synonyms:Ethylene glycol butyl vinyl ether;4223-11-4;1-(2-ethenoxyethoxy)butane;2-Butoxyethyl vinyl ether;Ethane, 1-butoxy-2-(vinyloxy)-;1-BUTOXY-2-VINYLOXY ETHANE;Vinyl 2-(butoxyethyl) ether;1-Butoxy-2-(vinyloxy)ethane;2-Butoxyethylvinyl ether;5AK3IYE5IJ;Butyl 2-vinyloxyethyl ether;HSDB 2825;EINECS 224-172-3;Butane, 1-(2-(ethenyloxy)ethoxy)-;Butane, 1-[2-(ethenyloxy)ethoxy]-;NSC 32633;NSC-32633;Butylvinylether ethylenglykolu [Czech];BRN 1702029;AI3-14413;3,6-Dioxa-1-decene;UNII-5AK3IYE5IJ;Butylvinylether ethylenglykolu;SCHEMBL42092;WLN: 4O2O1U1;DTXSID30195054;NSC32633;AKOS009156423;LS-65232

Chemical Property of Ethylene glycol butyl vinyl ether

Chemical Property:

• Vapor Pressure: 2.2mmHg at 25°C
• Refractive Index: n20/D 1.422(lit.)
• Boiling Point: 167.9°Cat760mmHg
• Flash Point: 41.9°C
• PSA: 18.46000
• Density: 0.856g/cm³
• LogP: 1.96320
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 144.115029749
• Heavy Atom Count: 10
• Complexity: 71.7

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 10-41
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> Other Monomers
• Canonical SMILES: CCCCOCCOC=C

Technology Process of Ethylene glycol butyl vinyl ether

There total 4 articles about Ethylene glycol butyl vinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.1%

1-bromo-butane (109-65-9) + ethyleneglycol vinyl ether (764-48-7) → ethylene glycol n-butyl vinyl diether (4223-11-4)

Guidance literature:

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In water;

Reference yield: 73.0%

2-Butoxyethanol (111-76-2,9004-77-7) + acetylene (74-86-2,25067-58-7) → ethylene glycol n-butyl vinyl diether (4223-11-4)

Guidance literature:

With potassium hydroxide; at 135 - 140 ℃; under 1137.7 - 2068.6 Torr;

Reference yield:

2-chloroetyl vinyl ether (110-75-8) + butan-1-ol (71-36-3) → ethylene glycol n-butyl vinyl diether (4223-11-4)

Guidance literature:

With sodium butanolate;

upstream raw materials:

2-Butoxyethanol

acetylene

2-chloroetyl vinyl ether

butan-1-ol

Downstream raw materials:

(2-ethenyloxyethyl)dimethylamine

tert-butyl vinyl ether

1-(4-methoxyphenyl)ethanone

benzyl vinyl ether

Refernces

• 1、 Trofimov, B. A.,Lavrov, V. I.,Parshina, L. N.,Grigorenko, V. I.,Maksimov, S. M.,et al.. "ALKYLATION OF MONOVINYL ETHERS OF DIOLS UNDER CONDITIONS OF INTERPHASE CATALYSIS". . p. 1671 - 1673. Retrieved 2007/10/02.