Tris(2,3-dichloropropyl) phosphate

Base Information

• Chemical Name: Tris(2,3-dichloropropyl) phosphate
• CAS No.: 78-43-3
• Molecular Formula: C9H15 Cl6 O4 P
• Molecular Weight: 430.907
• European Community (EC) Number: 201-117-1
• UNII: 29WKV18KR6
• DSSTox Substance ID: DTXSID7023805
• Nikkaji Number: J2.407D
• Wikidata: Q27254448
• Mol file: 78-43-3.mol

Synonyms:tris(2,3-dichloropropyl)phosphate

Chemical Property of Tris(2,3-dichloropropyl) phosphate

Chemical Property:

• Vapor Pressure: 6.5E-09mmHg at 25°C
• Boiling Point: 480.1°C at 760 mmHg
• Flash Point: 407°C
• PSA: 54.57000
• Density: 1.487g/cm³
• LogP: 4.68290
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 429.880962
• Heavy Atom Count: 20
• Complexity: 255

Purity/Quality:

99% ^*data from raw suppliers

TRIS(2,3-DICHLOROPROPYL)PHOSPHATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,N
• Hazard Codes: Xn,N
• Statements: 40-51/53
• Safety Statements: 36/37-61

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Organophosphates, Other
• Canonical SMILES: C(C(CCl)Cl)OP(=O)(OCC(CCl)Cl)OCC(CCl)Cl
• Uses: Flame-retardant in plastics and as a secondary plasticizer.

Technology Process of Tris(2,3-dichloropropyl) phosphate

There total 2 articles about Tris(2,3-dichloropropyl) phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.1%

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → tris(2,3-dichloropropyl)phosphate (78-43-3)

Guidance literature:

With trichlorophosphate; at 10 ℃; for 2h; Autoclave; Reflux;

DOI:10.1016/j.cclet.2012.09.015

Reference yield:

→ tris(2,3-dichloropropyl)phosphate (78-43-3)

Guidance literature:

epichlorohydrin, POCl3, AlCl3;

upstream raw materials:

epichlorohydrin

Refernces

• 1、 Zhi, Hui Zhen,Shi, Hong Li,Hu, Yun,Xia, Ke Dan,Zhang, Peng,Yang, Jin Fei. "Epoxy ether cleaving reactions catalyzed by supporting Lewis acidic ionic liquid". . p. 1217 - 1220,4. Retrieved 2020/09/16.