4,4'-Oxybisbenzoyl chloride

Base Information

• Chemical Name: 4,4'-Oxybisbenzoyl chloride
• CAS No.: 7158-32-9
• Molecular Formula: C14H8 Cl2 O3
• Molecular Weight: 295.122
• Hs Code.: 2916399090
• European Community (EC) Number: 808-159-5
• DSSTox Substance ID: DTXSID60221810
• Nikkaji Number: J624.403C
• Wikidata: Q72499320
• Mol file: 7158-32-9.mol

Synonyms:7158-32-9;4,4'-OXYBISBENZOYL CHLORIDE;4,4'-oxydibenzoyl chloride;4,4'-Oxybis(benzoyl chloride);4,4-OXY-DI-BENZOYLCHLORIDE;4-(4-carbonochloridoylphenoxy)benzoyl chloride;BENZOYL CHLORIDE, p,p'-OXYBIS-;BRN 0660719;p,p'-Oxybis(benzoyl chloride);4,4-Dicarboxylic acid diphenyl oxide dichloroanhydride;4.4-oxybisbenzoic chloride (DEDC);4-10-00-00432 (Beilstein Handbook Reference);4,4'-oxydibenzoylchloride;SCHEMBL272345;DTXSID60221810;Bis(4-chlorocarbonylphenyl) Ether;AMY10260;BCP30613;4,4'-Oxybis(benzoic acid chloride);MFCD00496619;AKOS003235664;4,4'-Bis(chlorocarbonyl)diphenyl Ether;AS-18522;LS-42611;FT-0706038;O0399;A837251;4-(4-chlorocarbonylphenoxy)benzoyl chloride;4,4'-Oxydibenzoyl chloride

Chemical Property of 4,4'-Oxybisbenzoyl chloride

Chemical Property:

• Melting Point: 22-23℃
• Boiling Point: 404℃
• Flash Point: 164℃
• PSA: 43.37000
• Density: 1.386
• LogP: 4.23690
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: soluble in Toluene
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 293.9850495
• Heavy Atom Count: 19
• Complexity: 298

Purity/Quality:

99% ^*data from raw suppliers

4,4'-Oxybis(benzoyl Chloride) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C(=O)Cl)OC2=CC=C(C=C2)C(=O)Cl
• Uses: 4,4'-OXYBISBENZOYL CHLORIDE is a useful research chemical.

Technology Process of 4,4'-Oxybisbenzoyl chloride

There total 4 articles about 4,4'-Oxybisbenzoyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

oxybis(benzoic acid) (2215-89-6) → 4,4'-bis(chlorocarbonyl)diphenyl oxide (7158-32-9)

Guidance literature:

With thionyl chloride; In N,N-dimethyl-formamide; toluene; at 95 ℃; for 3h;

Reference yield:

4-(4-formylphenoxy)benzaldehyde (2215-76-1) → 4,4'-bis(chlorocarbonyl)diphenyl oxide (7158-32-9)

Guidance literature:

With thionyl chloride;

DOI:10.1039/a805720f

Reference yield:

4-(4'-cyanophenoxy)benzonitrile (6508-04-9) → 4,4'-bis(chlorocarbonyl)diphenyl oxide (7158-32-9)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous H₂SO₄

2: SOCl₂

With thionyl chloride; sulfuric acid;

upstream raw materials:

oxybis(benzoic acid)

4-(4-formylphenoxy)benzaldehyde

4-(4'-cyanophenoxy)benzonitrile

Downstream raw materials:

(4'-phenylthio-4-benzoylphenyl) ether

4-(4-formylphenoxy)benzaldehyde

bis(tetrathiafulvalen-4-ylmethyl) 4,4'-oxybis(benzenecarboxylate)

4-(4-carbamoylphenoxyl)benzamide

Refernces

• 1、 Huang, Jian-Cai,Ye, Guang-Ming,Yu, Maoxing,Huang, Ruishan,Zhao, Zujin,Qin, Anjun,Wu, Shu-Ting,Xie, Zenghong. "Circularly Polarized Luminescence of Achiral Metal–Organic Colloids and Guest Molecules in a Vortex Field". supporting information. p. 6760 - 6766. Retrieved 2021/03/19.
• 2、 Ignatovich, Zh. V.,Ermolinskaya,Petushok,Katok, Ya. M.,Koroleva. "Synthesis of 4,4′-Oxydibenzoic Acid Amides and Sulfonamides Containing 2-Arylaminopyrimidine Moieties". . p. 2092 - 2097. Retrieved 2021/02/09.