Fenamiphos sulfone

Base Information

• Chemical Name: Fenamiphos sulfone
• CAS No.: 31972-44-8
• Molecular Formula: C13H22NO5PS
• Molecular Weight: 335.361
• Hs Code.: 2931900090
• European Community (EC) Number: 622-561-6
• UNII: 77I51XA8L2
• DSSTox Substance ID: DTXSID3037547
• Nikkaji Number: J124.968A
• Wikidata: Q27891497
• ChEMBL ID: CHEMBL3186568
• Mol file: 31972-44-8.mol

Synonyms:fenamiphos sulfone;fenamiphos sulfphone

Chemical Property of Fenamiphos sulfone

Chemical Property:

• Melting Point: 84-86°C
• Refractive Index: 1.521
• Boiling Point: 456.7 °C at 760 mmHg
• PKA: -0.48±0.70(Predicted)
• Flash Point: 230 °C
• PSA: 99.89000
• Density: 1.209 g/cm³
• LogP: 4.39160
• Storage Temp.: 2-8°C
• XLogP3: 2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 335.09563097
• Heavy Atom Count: 21
• Complexity: 473

Purity/Quality:

99% ^*data from raw suppliers

FenamiphosSulfone ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+； N
• Hazard Codes: T+,N
• Statements: 28-50/53
• Safety Statements: 22-28-36/37-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOP(=O)(NC(C)C)OC1=CC(=C(C=C1)S(=O)(=O)C)C

Technology Process of Fenamiphos sulfone

There total 2 articles about Fenamiphos sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfinyl)phenyl ester (31972-43-7,124793-11-9) → (1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfonyl)phenyl ester (31972-44-8)

Guidance literature:

With perfluoro cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); at 0 ℃; for 8h;

DOI:10.1016/0040-4020(95)00413-3

Reference yield:

4-hydroxy-2-methyl(methylsulfonyl)benzene (14270-40-7) + isopropylamine (75-31-0) → (1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfonyl)phenyl ester (31972-44-8)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1016/0040-4020(95)00413-3

upstream raw materials:

(1-methylethyl)phosphoramidic acid ethyl 3-methyl-4(methylsulfinyl)phenyl ester

4-hydroxy-2-methyl(methylsulfonyl)benzene

isopropylamine

Refernces