5-Nitro-1,2,3-benzenetricarboxylic acid

Base Information

• Chemical Name: 5-Nitro-1,2,3-benzenetricarboxylic acid
• CAS No.: 3807-81-6
• Molecular Formula: C9H5NO8
• Molecular Weight: 255.141
• Hs Code.: 2917399590
• Mol file: 3807-81-6.mol

Synonyms:Hemimelliticacid, 5-nitro- (6CI);

Chemical Property of 5-Nitro-1,2,3-benzenetricarboxylic acid

Chemical Property:

• Vapor Pressure: 8.97E-13mmHg at 25°C
• Melting Point: 208 °C
• Refractive Index: 1.698
• Boiling Point: 546.4 °C at 760 mmHg
• PKA: 2.09±0.30(Predicted)
• Flash Point: 240.4 °C
• PSA: 157.72000
• Density: 1.837 g/cm₃
• LogP: 1.21260
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

5-Nitro-1,2,3-benzenetricarboxylicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-Nitro-1,2,3-benzenetricarboxylic acid

There total 6 articles about 5-Nitro-1,2,3-benzenetricarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Tri-K-Salz von Hemimellitsaeure (15999-91-4,63507-68-6,66760-38-1) → 5-nitro-1,2,3-benzenetricarboxylic acid (3807-81-6)

Guidance literature:

With sulfuric acid; potassium nitrate; at 120 ℃; for 6h;

Reference yield:

benzene-1,2,3-tricarboxlic acid (569-51-7) → 5-nitro-1,2,3-benzenetricarboxylic acid (3807-81-6)

Guidance literature:

With sulfuric acid; potassium nitrate;

DOI:10.1002/hlca.19490320534

Reference yield:

1,2,3-trimethylbenzene (526-73-8) → 5-nitro-1,2,3-benzenetricarboxylic acid (3807-81-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 80 percent / NaOH, KMnO₄ / H₂O / 2 h / Heating

2: 88 percent / 1M KOH / propan-2-ol

3: 80 percent / conc. H₂SO₄, KNO₃ / 6 h / 120 °C

With potassium hydroxide; sodium hydroxide; potassium permanganate; sulfuric acid; potassium nitrate; In water; isopropyl alcohol;

upstream raw materials:

benzene-1,2,3-tricarboxlic acid

Tri-K-Salz von Hemimellitsaeure

1-Hydroxy-3.5-diacetoxymethyl-7-nitro-1H-benzopyran-⁽²⁾

1,2,3-trimethylbenzene

Refernces

• 1、 Capassso, Renato,Randazzo, Giacomino,Stipani, Italo,Zara, Vincenzo,Palmieri, Ferdinando. "INTERACTION OF 5-AZIDO-1,2,3-BENZENETRICARBOXYLIC ACID WITH THE MITOCHONDRIAL TRICARBOXYLATE CARRIER". . p. 449 - 452. Retrieved 2007/10/02.
• 2、 -. "1,3,5- Or 1,3,6-naphthalenetriyltris(sulfonylimino)aryl acids and salts". . . Retrieved 2008/06/13.