1,4-Bis((vinyloxy)methyl)cyclohexane

Base Information

• Chemical Name: 1,4-Bis((vinyloxy)methyl)cyclohexane
• CAS No.: 17351-75-6
• Molecular Formula: C₁₂H₂₀O₂
• Molecular Weight: 196.29
• European Community (EC) Number: 413-370-7,682-397-6
• DSSTox Substance ID: DTXSID0044604
• Nikkaji Number: J2.099.347B,J468.362E
• ChEMBL ID: CHEMBL3183650
• Mol file: 17351-75-6.mol

Synonyms:17351-75-6;1,4-Bis((vinyloxy)methyl)cyclohexane;1,4-bis(ethenoxymethyl)cyclohexane;1,4-cyclohexanedimethanol divinyl ether;CHDVE;Cyclohexane, 1,4-bis[(ethenyloxy)methyl]-;1,4-Bis[(ethenyloxy)methyl]cyclohexane;DTXSID0044604;Divinyloxy 1,4-cyclohexanedimethanol;1,4-bis[(vinyloxy)methyl]cyclohexane;Cyclohexane, 1,4-bis((ethenyloxy)methyl)-;CHVE;SCHEMBL238829;CHEMBL3183650;DTXCID8024604;SCHEMBL14409655;SCHEMBL14488382;SCHEMBL22187599;DQNSRQYYCSXZDF-HAQNSBGRSA-N;DQNSRQYYCSXZDF-UHFFFAOYSA-N;Tox21_302720;MFCD00080497;AKOS015913877;NCGC00256734-01;AS-76830;CAS-17351-75-6;FT-0637543;1beta,4alpha-Bis[(vinyloxy)methyl]cyclohexane;trans-1,4-cyclohexanedimethanol divinyl ether;E85277;EC 413-370-7;1,4-Bis(Hydroxymethyl) cyclohexane divinylether

Chemical Property of 1,4-Bis((vinyloxy)methyl)cyclohexane

Chemical Property:

• Appearance/Colour: COLORLESS LIQUID
• Vapor Pressure: 0.0696mmHg at 25°C
• Melting Point: 6ºC
• Refractive Index: n20/D 1.472(lit.)
• Boiling Point: 126 ºC (14 mmHg)
• Flash Point: >110 ºC
• PSA: 18.46000
• Density: 0.919
• LogP: 3.25710
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 196.146329876
• Heavy Atom Count: 14
• Complexity: 149

Purity/Quality:

99.9% ^*data from raw suppliers

1,4-Cyclohexanedimethanol divinyl ether, mixture of isomers 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N
• Statements: 43-51/53-38
• Safety Statements: 24-37-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=COCC1CCC(CC1)COC=C

Technology Process of 1,4-Bis((vinyloxy)methyl)cyclohexane

There total 2 articles about 1,4-Bis((vinyloxy)methyl)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

trans-1,4-cyclohexanedimethanol + acetylene (74-86-2,25067-58-7) → trans-1,4-cyclohexanedimethanol divinyl ether (17351-75-6)

Guidance literature:

With potassium hydroxide; at 160 ℃; for 23h; under 14251.4 Torr; Inert atmosphere;

Reference yield: 70.0%

bis-1,4-(hydroxymethyl)cyclohexane (105-08-8) + acetylene (74-86-2,25067-58-7) → 1,4-cyclohexanedimethanol divinyl ether (17351-75-6)

Guidance literature:

With potassium hydroxide; at 160 ℃; for 9h; under 15001.5 Torr; Autoclave; Inert atmosphere; Large scale;

Reference yield:

trans-1,4-cyclohexanedimethanol divinyl ether (17351-75-6) → trans-1,4-cyclohexanedimethanol diethyl ether

Guidance literature:

With 5% palladium on Al₂O₃; hydrogen; at 30 ℃; for 10h; under 15001.5 Torr;

upstream raw materials:

bis-1,4-(hydroxymethyl)cyclohexane

acetylene

Downstream raw materials:

1,4-cyclohexanedimethanol diethyl ether

Refernces