Nickel oxide

Base Information

• Chemical Name: Nickel oxide
• CAS No.: 1313-99-1
• Deprecated CAS: 185461-96-5,203645-17-4,339311-41-0,2214286-18-5,2566882-23-1,2644645-41-8,2706615-06-5
• Molecular Formula: NiO
• Molecular Weight: 74.6894
• Hs Code.: 28254000
• European Community (EC) Number: 215-215-7,234-323-5
• ICSC Number: 0926
• UN Number: 3288,3077
• DSSTox Substance ID: DTXSID001033642
• Wikipedia: Nickel(II) oxide,Nickel(II)_oxide,Bunsenite
• Wikidata: Q411221
• NCI Thesaurus Code: C45864
• Mol file: 1313-99-1.mol

Synonyms:nickel monoxide;nickel oxide;nickel(II)oxide

Chemical Property of Nickel oxide

Chemical Property:

• Appearance/Colour: olive green crystals
• Melting Point: 1960 °C
• PSA: 17.07000
• Density: 6.67 g/mL at 25 °C(lit.)
• LogP: -0.11880
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 73.930256
• Heavy Atom Count: 2
• Complexity: 2
• Transport DOT Label: Poison

Purity/Quality:

99% ^*data from raw suppliers

Nickel(II) oxide, green, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,Xi
• Hazard Codes: T,Xi
• Statements: 49-43-53-48/23-36/37
• Safety Statements: 53-45-61-36/37-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Nickel Compounds, Inorganic
• Canonical SMILES: O=[Ni]
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
• Effects of Short Term Exposure: The substance may be irritating to the eyes, respiratory tract and skin.
• Effects of Long Term Exposure: Repeated or prolonged contact may cause skin sensitization. Repeated or prolonged inhalation may cause asthma. The substance may have effects on the lungs and nasal mucous membrane. This substance is carcinogenic to humans if inhaled.
• Physical Properties: Green cubic crystals; transforms to a grayish black octahedral form, known as black oxide, when strongly ignited; black oxide has a metallic luster; density of green oxide is 6.72 g/cm3; Mohs hardness 5.5; melts at 1955°C; insoluble in water; soluble in acids at ordinary temperatures; black form dissolves in hot acids.
• Uses: Nickel (II) oxide is used in the ceramic industry for making frit, ferrites, and coloring porcelain. The oxide in sinter form is used in the production of nickel- steel alloys. It supplies oxygen to the melt for removal of carbon as carbon dioxide. Some other important uses of Nickel (II) oxide include preparation of many nickel salts, specialty chemicals, and nickel catalysts. It also is used as an electrode in fuel cells. Nickel salts, porcelain painting, fuel cell electrodes. Nickel(II) oxide is used in the preparation of nickel alloys including nickel steel alloys, manufacture of glass and porcelain paints. Further nickel oxide is the main component in nickel-iron battery (Edison battery), nickel-cadmium rechargeable battery, and also used in ceramic industry for making frits and porcelain glazes. It also acts as a hydrogenation catalyst. NiO/CNTs (nickel oxide/carbon nanotubes) could be a potential cathode catalyst for oxygen reduction reaction (ORR) in microbial fuel cells (MFCs). It is blended with other high purity oxides and used in a variety of semiconductor applications such as thermistors and varistors. Nickel oxide nanowires have been studied for use in magnetic memory devices; as well as in luminescent materials.

Technology Process of Nickel oxide

There total 1653 articles about Nickel oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel hydroxide carbonate + aluminium (7429-90-5) → nickel(II) oxide (1313-99-1) + aluminum oxide (1333-84-2,1344-28-1) + aluminium oxide hydrate

Guidance literature:

In solid; byproducts: aluminium nickel alloy; ball milling of a mixt of Al and nickel salt in air; X-ray diffraction;

DOI:10.1023/A:1020613902812

Reference yield:

4Ni(2+)*2Zn(2+)*2Al(3+)*16OH(1-)*CO3(2-)*4H2O=Ni4Zn2Al2(OH)16CO3*4H2O → nickel(II) oxide (1313-99-1) + aluminum oxide (1333-84-2,1344-28-1) + carbon dioxide (124-38-9,18923-20-1) + water (7732-18-5) + zinc(II) oxide

Guidance literature:

In neat (no solvent); thermal decomposition under N2; TG, DTG, MS;

DOI:10.1007/s10973-005-0749-8

Reference yield:

5Ni(2+)*Zn(2+)*2Al(3+)*16OH(1-)*CO3(2-)*4H2O=Ni5ZnAl2(OH)16CO3*4H2O → nickel(II) oxide (1313-99-1) + aluminum oxide (1333-84-2,1344-28-1) + carbon dioxide (124-38-9,18923-20-1) + water (7732-18-5) + zinc(II) oxide

Guidance literature:

In neat (no solvent); thermal decomposition under N2; TG, DTG, MS;

DOI:10.1007/s10973-005-0749-8

upstream raw materials:

lithium acetate dihydrate

nickel(II) acetate tetrahydrate

aluminium

sodium hydroxide

Downstream raw materials:

1,1,1-tri(hydroxymethyl)propane

nickel dichloride

nickel

tetracarbonyl nickel

Refernces

• 1、 Martirosyan,Filimonov,Nersesyan,Luss, Dan. "Electric field formation during combustion of single metal particles". . p. J9-J16. Retrieved 2003.
• 2、 Farhadi, Saeid,Roostaei-Zaniyani, Zeinab. "Preparation and characterization of NiO nanoparticles from thermal decomposition of the [Ni(en)3](NO3)2 complex: A facile and low-temperature route". . p. 971 - 975. Retrieved 2011.
• 3、 Berbenni, Vittorio,Milanese, Chiara,Bruni, Giovanna,Marini, Amedeo. "The combined effect of mechanical and thermal energy on the solid-state formation of NiFe2O4 from the system 2NiCO3·3Ni(OH)2·4H2O-FeC2O4·2H2O". . p. 86 - 90. Retrieved 2008.
• 4、 Lin, Tie Jun,Meng, Xuan,Shi, Li. "Catalytic hydrocarboxylation of acetylene to acrylic acid using Ni2O3 and cupric bromide as combined catalysts". . p. 77 - 83. Retrieved 2015.
• 5、 Maniam, Palanikumar,Stock, Norbert. "Investigation of porous ni-based metal-organic frameworks containing paddle-wheel type inorganic building units via high-throughput methods". . p. 5085 - 5097. Retrieved 2011.
• 6、 Kopylovich,Kirillov,Baev. "Thermolysis of Coprecipitated Copper(II)-Nickel(II) Hydroxides". . p. 12 - 17. Retrieved 2001.
• 7、 Wu, Ming-Cheng,Lee, Chi-Shen. "Synthesis and thermal decomposition of Zn(tda)H2O [tda = S(CH2COO)22-]". . p. 9634 - 9636. Retrieved 2006.
• 8、 Lin, Feini,Wang, Hui,Wang, Gang. "Facile Synthesis of Hollow Polyhedral (Cubic, Octahedral and Dodecahedral) NiO with Enhanced Lithium Storage Capabilities". . p. 207 - 216. Retrieved 2016.
• 9、 Swamy,Pola, Someshwar. "Spectroscopic studies on Co(II), Ni(II), Cu(II) and Zn(II) complexes with a N4-macrocylic ligands". . p. 929 - 933. Retrieved 2008.
• 10、 Li, Yanwei,Zheng, Yuanyuan,Yao, Jinhuan,Xiao, Jianrong,Yang, Jianwen,Xiao, Shunhua. "Facile synthesis of nanocrystalline-assembled nest-like NiO hollow microspheres with superior lithium storage performance". . p. 31287 - 31297. Retrieved 2017.