Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)-

Base Information

• Chemical Name: Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)-
• CAS No.: 58473-78-2
• Deprecated CAS: 148044-18-2,956771-58-7,956771-58-7
• Molecular Formula: C46H46N2
• Molecular Weight: 626.885
• Hs Code.: 29215900
• European Community (EC) Number: 261-274-7
• DSSTox Substance ID: DTXSID0069258
• Nikkaji Number: J296.952A
• Wikidata: Q72459981
• Mol file: 58473-78-2.mol

Synonyms:58473-78-2;TAPC;4,4'-Cyclohexylidenebis[N,N-bis(4-methylphenyl)aniline];Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)-;4,4'-(Cyclohexane-1,1-diyl)bis(N,N-di-p-tolylaniline);EINECS 261-274-7;4-methyl-N-[4-[1-[4-(4-methyl-N-(4-methylphenyl)anilino)phenyl]cyclohexyl]phenyl]-N-(4-methylphenyl)aniline;4,4'-Cyclohexylidenebis(N,N-bis(p-tolyl)aniline);1,1-Bis[4-[N,N-di(p-tolyl)amino]phenyl]cyclohexane;4,4-(Cyclohexane-1,1-diyl)bis(N,N-di-p-tolylaniline);di-[4-(N,N-ditolyl-amino)-phenyl]cyclohexane;4,4'-Cyclohexylidenebis[N,N-di(p-tolyl)aniline];1,1-bis(4-bis(4-methylphenyl)aminophenyl)cyclohexane;Benzenamine, 4,4'-cyclohexylidenebis(N,N-bis(4-methylphenyl)-;Di-[4-(N,N-ditolyl-amino)-phenyl]cyclohexan;1,1-Bis(4-di-p-tolylaminophenyl)cyclohexane;4,4'-cyclohexylidenebis[N,N-bis(p-tolyl)aniline];4,4'-cyclohexylidenebis(n,n-bis(4-methylphenyl)aniline);4,4'-cyclohexylidenebis(N,N-bis(4-methylphenyl)benzenamine);4,4'-Cyclohexylidenebis[N,N-bis(4-methylphenyl)benzenamine];C46H46N2;1,1-bis(4-di-p-tolylaminophenyl)cyclohexane;SCHEMBL39661;DTXSID0069258;MFCD01310666;AKOS015840440;C46-H46-N2;CS-W011423;AC-27907;AS-39327;B2079;B3146;FT-0606074;1,1-bis[4-(di-p-tolylamino)phenyl]cyclohexane;Di-[4-(N,N-di-p-tolyl-amino)-phenyl]cyclohexane;1,1-Bis[4-[N,N-di(p-toly)amino]phenyl]cyclohexane;1,1- Bis[4-[N,N'-di(p-tolyl)amino]phenyl]cyclohexane;1,1-Bis[4-(N,N-di(p-tolyl)amino)phenyl]cyclohexane, 98%;4,4'-Cyclohexylidenebis[N,N-bis(4-methylphenyl)benzenamine], 97%;1,1-Bis[4-[N,N-di(p-toly)amino]pnenyl]cyclohexane, >99.0%(HPLC);1,1-Bis[4-[N,N-di(p-tolyl)amino]phenyl]cyclohexane (purified by sublimation);1,1-Bis[4-[N,N-di(p-tolyl)amino]phenyl]cyclohexane, (purified by sublimation);benzenamine, N,N'-(cyclohexylidenedi-4,1-phenylene)bis[4-methyl-N-(4-methylphenyl)-;N,N'-(cyclohexane-1,1-diyldibenzene-4,1-diyl)bis[4-methyl-N-(4-methylphenyl)aniline]

Chemical Property of Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)-

Chemical Property:

• Melting Point: 186 °C
• Boiling Point: 755 °C at 760 mmHg
• PKA: -1.57±0.60(Predicted)
• Flash Point: 328.8 °C
• PSA: 6.48000
• Density: 1.118 g/cm³
• LogP: 13.11000
• Storage Temp.: 2-8°C
• Solubility.: soluble in Dimethylformamide,Tetrahydrofuran
• XLogP3: 14.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 626.366099476
• Heavy Atom Count: 48
• Complexity: 807

Purity/Quality:

98% ^*data from raw suppliers

Di-[4-(N,N-ditolylamino)phenyl]cyclohexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C4(CCCCC4)C5=CC=C(C=C5)N(C6=CC=C(C=C6)C)C7=CC=C(C=C7)C
• Description: 1,1-Bis[(di-4-tolylamino)phenyl]cyclohexane, known as TAPC, has been?widely used as a hole transport material in organic light-emitting diodes (OLEDs) due to its?high hole mobility.
• Uses: This material is a popular Hole Transport Layer material for OLED devices.

Technology Process of Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)-

There total 1 articles about Benzenamine, 4,4'-cyclohexylidenebis[N,N-bis(4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

4-tolyl iodide (624-31-7) + 1,1-bis-(4-aminophenyl)cyclohexane (3282-99-3) → 1,1-bis[4-(di-p-tolylamino)phenyl]cyclohexane (58473-78-2)

Guidance literature:

With 18-crown-6 ether; potassium carbonate; In 1,2-dichloro-benzene; at 150 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1107/S2053229619007101

upstream raw materials:

4-tolyl iodide

1,1-bis-(4-aminophenyl)cyclohexane

Refernces