μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))

Base Information

• Chemical Name: μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))
• CAS No.: 75249-87-5
• Molecular Formula: C₈₉H₅₆Fe₂N₈
• Molecular Weight: 1349.17
• Mol file: 75249-87-5.mol

Synonyms:μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))

Chemical Property of μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))

There total 11 articles about μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

meso-tetraphenylporphyrin iron(III) chloride (16456-81-8,170645-84-8) + trichloromethyltrimethylsilane (5936-98-1) → μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV)) (75249-87-5)

Guidance literature:

With iron; In methanol; dichloromethane; reflux for few min;

DOI:10.1016/S0022-328X(81)80004-6

Reference yield: 90.0%

5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) + carbon tetraiodide (507-25-5) + iron (7439-89-6) → [Fe((C6H5)4C20H8N4)]2C*2H2O (75249-87-5)

Guidance literature:

In methanol; dichloromethane; Fe-complex was dissolved in CH2Cl2-MeOH under Ar in the presence of Fe,ligand was added under Ar, soln. was stirred at 20°C for 1 h; filtered, washed with H2O, dried over Na2SO4, evapd., solid was dissolved in CH2Cl2-MeOH (or EtOH), chromd. on silica gel with C6H6-CH2Cl2; elem. anal.;

DOI:10.1021/ic50223a076

Reference yield: 75.0%

5,10,15,20-tetraphenyl-21H,23H-porphine iron(lll) chloride (16456-81-8) + carbon tetraiodide (507-25-5) → (Fe(C20H8N4(C6H5)4))2C (75249-87-5)

Guidance literature:

With methanol; sodium tetrahydroborate; In dichloromethane; large excess of NaBH4 added to mixt. of Fe-complex in anaerobic CH2Cl2 under Ar, anaerobic CH3OH added, freshly prepared CI4 added, stirred for2 h; according to Mansuy, D.; Lecomte, J.-P.; Chottard, J.-C.; Bartoli,J.-F. Inorg. Chem. 1981, 20, 3119; washed with water, dried over Na2SO4, evapd., recrystd from toluene-hexane; detected by TLC, UV-vis and NMR spectra;

upstream raw materials:

trichloromethyltrimethylsilane

meso-tetraphenylporphyrin iron(III) chloride

iron(III)phthalocyanine chloride

5,10,15,20-tetraphenyl-21H,23H-porphine iron(lll) chloride

Downstream raw materials:

Fe(tetraphenylporphyrin)Br

meso-tetraphenylporphyrin iron(III) chloride

meso-tetraphenylporphyrinatobis(pyridine)iron(II)

Refernces

• 1、 Zaitseva,Zdanovich,Kudrik,Koifman. "Coordination properties of μ-carbidodimeric iron(IV) 2,3,7,8,12,13,17,18-octapropyltetraazaporphyrinate and 5,10,15,20-tetraphenylporphyrinate in reactions with nitrogen-containing bases". . p. 1257 - 1266. Retrieved 2017/09/29.
• 2、 Lan?on,Kadish. "Electrochemistry of the μ-carbido iron tetraphenylporphyrin dimer, ((TPP)Fe)2C, in nonaqueous media. Evidence for axial ligation by pyridine". . p. 3942 - 3947. Retrieved 2008/10/08.