(4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate

Base Information

• Chemical Name: (4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate
• CAS No.: 25646-77-9
• Molecular Formula: C11H18N2O^.H2SO4
• Molecular Weight: 292.356
• Hs Code.: 29221980
• European Community (EC) Number: 247-162-0,248-780-3
• UNII: BS668SJ6PT
• DSSTox Substance ID: DTXSID80897435
• Wikipedia: Color_Developing_Agent_4
• Wikidata: Q30161489
• Mol file: 25646-77-9.mol

Synonyms:25646-77-9;4-(N-Ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine sulfate;Kodak CD 4;2-((4-Amino-3-methylphenyl)(ethyl)amino)ethanol sulfate;(4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate;N4-Ethyl-N4-(2-hydroxyethyl)-2-methyl-1,4-phenylenediamine Sulfate;CD 4;PPD 4 4;EINECS 247-162-0;28020-34-0;BS668SJ6PT;2-[(4-Amino-3-methylphenyl)ethylamino]ethanol Sulfate;2-(4-amino-N-ethyl-3-methylanilino)ethanol;sulfuric acid;PPD 44;N4-Ethyl-N4-(2-hydroxyethyl)-2-methyl-1,4-phenylenediamine sulfate salt;EINECS 248-780-3;2-((4-Amino-3-methylphenyl)ethylamino)ethanol sulfate;N5-Ethyl-N5-(2'-hydroxyethyl)toluene-2,5-diammonium sulfate;Ethanol, 2-((4-amino-3-methylphenyl)ethylamino)-, sulfate (1:1) (salt);2-[(4-Amino-3-methylphenyl)(ethyl)-amino]ethanol sulfate;Ethanol, 2-((4-amino-3-methylphenyl)ethylamino)-, sulfate (1:?);Ethanol, 2-((4-amino-3-methylphenyl)ethylamino)-, sulfate (salt);Ethanol, 2-[(4-amino-3-methylphenyl)ethylamino]-, sulfate (salt);Ethanol, 2-((4-amino-3-methylphenyl)ethylamino)-, sulfate (1:1);Ethanol, 2-[(4-amino-3-methylphenyl)ethylamino]-, sulfate (1:1);Ethanol, 2-[(4-amino-3-methylphenyl)ethylamino]-, sulfate (1:1) (salt);n4-Ethyl-n4-(2-hydroxyethyl)-2-methyl-1,4-phenylenediamine sulfate salt suitable for photographic applications;UNII-BS668SJ6PT;PPD 4;C11H18N2O.xH2O4S;SCHEMBL2140481;C11H18N2O.H2O4S;DTXSID80897435;BCP10488;MFCD00035563;AKOS015890578;AC-8318;CS-W012177;C11-H18-N2-O.H2-O4-S;C11-H18-N2-O.x-H2-O4-S;LS-14006;LS-66432;E0657;FT-0616835;E76058;A817945;J-016088;Q30161489;(4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulfate;2-((4-Amino-3-methylphenyl)(ethyl)amino)ethanolsulfate;4-amino-3-methyl-N-(beta-hydroxyethyl)-N-ethylaniline sulfate;4-amino-3-methyl-N-ethyl-N-(beta-hydroxyethyl)aniline sulfate;Ethanol, 2-(4-amino-N-ethyl-m-toluidino)-, sulfate (salt);N-ethyl-N-hydroxyethyl-3-methyl-1,4-phenylenediamine sulfate;(4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulfate (1:1);2-[(4-azanyl-3-methyl-phenyl)-ethyl-amino]ethanol;Etanol, 2-[(4-amino-3-metilfenil) etilamino]-, sulfato (1:1);ETHANOL, 2-((4-AMINO-3-METHYLPHENYL)ETHYLAMINO)-, SULFATE (1:1)(SALT);N4-Ethyl-N4-(2-hydroxyethyl)-2-methyl-1,4-phenylenediamine sulfate salt, suitable for photographic applications

Chemical Property of (4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate

Chemical Property:

• Appearance/Colour: beige fine crystalline powder
• Melting Point: 155 °C
• Boiling Point: 364.3 °C at 760 mmHg
• Flash Point: 174.1 °C
• PSA: 132.47000
• Density: 1.1g/cm3
• LogP: 2.40500
• Storage Temp.: -20°C
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 4
• Exact Mass: 292.10929292
• Heavy Atom Count: 19
• Complexity: 245

Purity/Quality:

99% ^*data from raw suppliers

CD4 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T, N, Xi
• Hazard Codes: T,N,Xi
• Statements: 25-43-48/22-50/53-36/37/38
• Safety Statements: 24-37-45-60-61-36-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aromatic
• Canonical SMILES: CCN(CCO)C1=CC(=C(C=C1)N)C.OS(=O)(=O)O
• Description: CD4 is a color-film developer, and both an allergen and an irritant in photographers. Cross reactivity is possible with Disperse Blue 124, Disperse Blue 106, and Disperse red 17.
• Uses: 4-(N-Ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine sulfate is used as a color developer for Kodacolor II film, identicaI to Flexicolor or C-41 process; color developer for use in color microautoradiography for color development of immunogold-labeled antibodies.

Technology Process of (4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate

There total 2 articles about (4-Ammonio-m-tolyl)ethyl(2-hydroxyethyl)ammonium sulphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

i-propyl nitrite (541-42-4) + N-ethyl-N-(2-hydroxyethyl)-3-methylaniline (91-88-3) → 2-[(4-amino-3-methylphenyl)(ethyl)amino]ethanol sulfate (25646-77-9,28020-34-0)

Guidance literature:

With sulfuric acid; palladium-carbon; In ethanol; isopropyl alcohol;

Reference yield: 100.0%

→ 2-[(4-amino-3-methylphenyl)(ethyl)amino]ethanol sulfate (25646-77-9,28020-34-0)

Guidance literature:

Reference yield: 52.0%

2-[(4-amino-3-methylphenyl)(ethyl)amino]ethanol sulfate (25646-77-9,28020-34-0) + edaravone (89-25-8) → 4-<-4--2-methylphenylimino>-3-methyl-1-phenyl-2-pyrazolin-5-on (104525-76-0)

Guidance literature:

With potassium ferrocyanide; In water; Ambient temperature;

upstream raw materials:

i-propyl nitrite

N-ethyl-N-(2-hydroxyethyl)-3-methylaniline

Downstream raw materials:

4-<4'--2-methylphenylimino>-1,4-dihydronaphthylidenemalononitrile

4-<-4--2-methylphenylimino>-3-methyl-1-phenyl-2-pyrazolin-5-on

2-{[4-(2-amino-5-butoxy-4-iminocyclohexa-2,5-dienylideneamino)-3-methylphenyl]ethylamino}ethanol

2-{4-[ethyl-(2-hydroxyethyl)amino]2-methylphenylamino}-4-{4-[ethyl-(2-hydroxyethyl)amino]-2-methyl phenylimino}-5-phenylaminocyclohexa-2,5-dienone

Refernces

• 1、 -. "Process for producing N,N-disubstituted p-phenylenediamine derivative sulfate". . . Retrieved 2008/06/13.