N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride

Base Information

• Chemical Name: N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride
• CAS No.: 1497-49-0
• Molecular Formula: C17H17ClN2
• Molecular Weight: 284.788
• Hs Code.: 2921.42
• Mol file: 1497-49-0.mol

Synonyms:N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride

Chemical Property of N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride

Chemical Property:

• Appearance/Colour: bordeaux to purple powder
• Vapor Pressure: 8.36E-08mmHg at 25°C
• Melting Point: 152 °C
• Boiling Point: 402.3 °C at 760 mmHg
• Flash Point: 197.1 °C
• PSA: 24.39000
• Density: 0.95 g/cm³
• LogP: 5.44590
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Solubility.: Chloroform (Slightly), DMSO (Slightly)
• Water Solubility.: Soluble in methanol. Insoluble in water..
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 284.1080262
• Heavy Atom Count: 20
• Complexity: 276

Purity/Quality:

99% ^*data from raw suppliers

GlutacondianilHydrochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xn,Xi
• Statements: 36/37/38-20/21/22
• Safety Statements: 36/37/39-26-37/39-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)NC=CC=CC=[NH+]C2=CC=CC=C2.[Cl-]
• Uses: Glutacondianil Hydrochloride is used as a reagent in the synthesis of novel vinylsulfone cyanine dyes used for labelling biomolecules. Dyes and metabolites.

Technology Process of N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride

There total 14 articles about N-(5-anilino-penta-2,4-dien-1-ylidene)anilinium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

pyridine (110-86-1) + perchloro-2-cyclopentene-1-one (2514-52-5) + aniline (62-53-3) → 2,4,4,5,5-Pentachloro-3-(phenylamino)-2-cyclopenten-1-one (61108-14-3) + 2,4,4,5,5-Pentachloro-3-amino-2-cyclopenten-1-one (60592-72-5) + glutacondianil hydrochloride (1497-49-0)

Guidance literature:

In 1,4-dioxane; for 4h;

Reference yield:

pyridine (110-86-1) → glutacondianil hydrochloride (1497-49-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 94 percent / acetonitrile / 3.5 h / 15 °C

2: 2.) HCl / 1.) H₂O, reflux, 5 min, 2.) H₂O, pH=1

With hydrogenchloride; In acetonitrile;

DOI:10.1016/S0040-4020(98)00265-8

Reference yield:

5-(2,4-dinitro-anilino)-penta-2,4-dienal (53405-99-5) → glutacondianil hydrochloride (1497-49-0)

Guidance literature:

Multi-step reaction with 2 steps

1: glacial acetic acid; hydrogen chloride / 100 °C / im Rohr

2: alcohol

With hydrogenchloride; ethanol; acetic acid;

upstream raw materials:

pyridine

N-phenyl-benzimidoyl chloride

aniline

p-toluenesulfonyl chloride

Downstream raw materials:

2,4,6-tribromoaniline

aniline

N-[(1E,3E)-6,6-dicyano-1,3,5-hexatrienyl]-N-phenylacetamide

4-(1,1-dimethyl-2-(6-(N-phenylacetamido)hexa-1,3,5-trien-1-yl)-1H-benzo[e]indol-3-ium-3-yl)butane-1-sulfonate

Refernces

• 1、 Makin, S. M.,Kruglikova, R. I.,Lonina, N. N.. "CHEMISTRY OF ENOL ETHERS. AMINOFORMYLATION OF SILYLENOL AND SILYLDIENOL ETHERS". . p. 627 - 629. Retrieved 2007/10/02.
• 2、 Simonov, V. D.,Chernova, L. N.,Akhmerova, S. G.,Yasman, Ya. B.. "REACTIONS OF PERCHLORO-2-CYCLOPENTEN-1-ONE AND PERCHLORO-4-CYCLPENTENE-1,3-DIONE WITH PYRIDINE AND QUINOLINE DERIVATIVES". . p. 1974 - 1978. Retrieved 2007/10/02.