Methyl 2-[4-(bromomethyl)phenyl]benzoate

Base Information Edit

Chemical Name:Methyl 2-[4-(bromomethyl)phenyl]benzoate
CAS No.:114772-38-2
Molecular Formula:C15H13BrO2
Molecular Weight:305.171
Hs Code.:29151300
European Community (EC) Number:601-325-6
DSSTox Substance ID:DTXSID70921490
Nikkaji Number:J2.649.802C
Wikidata:Q72488681
Mol file:114772-38-2.mol

Synonyms:114772-38-2;Methyl 2-[4-(bromomethyl)phenyl]benzoate;Methyl 4'-bromomethyl biphenyl-2-carboxylate;Methyl 4'-(Bromomethyl)biphenyl-2-carboxylate;METHYL 4'-(BROMOMETHYL)-[1,1'-BIPHENYL]-2-CARBOXYLATE;Methyl 4'-bromomethylbiphenyl-2-carboxylate;Methyl 4'-bromomethyl-biphenyl-2-carboxylate;4'-Bromomethyl-(1,1'-biphenyl)-2-carboxylic acid methyl ester;Methyl 4'-bromomethyl-2-biphenylcarboxylate;[1,1'-BIPHENYL]-2-CARBOXYLIC ACID, 4'-(BROMOMETHYL)-, METHYL ESTER;4'-Bromomethylbiphenyl-2-carboxylic Acid, Methyl Ester;MFCD06200816;Methyl 4/'-bromomethylbiphenyl-2-carboxylate;4'-bromomethylbiphenyl-2-carboxylic acid methyl ester;Methyl 2-(4-(bromomethyl)phenyl)benzoate;EC 601-325-6;Methyl 4'-(bromomethyl)[1,1'-biphenyl]-2-carboxylate;methyl 4'-(bromomethyl)-(1,1'-biphenyl)-2-carboxylate;2'-(Methoxycarbonyl)biphenyl-4-ylmethyl Bromide;Methyl 2-(4'-Bromomethylphenyl)benzoate;SCHEMBL562;2-[4-(Bromomethyl)phenyl]benzoic Acid Methyl Ester;RMXGTMRDXKUUDJ-UHFFFAOYSA-;DTXSID70921490;RMXGTMRDXKUUDJ-UHFFFAOYSA-N;BCP12011;4'-bromomethyl-2-carbomethoxybiphenyl;AKOS015888233;AB23054;AC-2016;AM90278;methyl 2-(4-bromomethylphenyl)benzoate;methyl 2-(4'-bromomethlphenyl)benzoate;4-bromomethyl-2'-methoxycarbonylbiphenyl;methyl 2-(4'-bromomethylpbenyl)benzoate;Methyl2-[4-(bromomethyl)phenyl]benzoate;4-bromomethyl-2'-methoxycarbonyl-biphenyl;AS-11906;SY035596;FT-0642791;M1806;methyl 4'-(bromomethyl)-biphenyl-2-carboxylate;EN300-7375583;A803229;methyl 4'-bromomethyl-1,1'-biphenyl-2-carboxylate;Q-201376;4'-(Bromomethyl)biphenyl-2-carboxylic Acid Methyl Ester;methyl 4'-(bromomethyl)-(1,1'-biphenyl)-2 -carboxylate;[(2'-(methoxycarbonyl)-(1,1'-biphenyl)-4-yl)-methyl]-bromide;Methyl 4 inverted exclamation mark -(Bromomethyl)biphenyl-2-carboxylate;4 inverted exclamation mark -Bromomethylbiphenyl-2-carboxylic Acid, Methyl Ester;InChI=1/C15H13BrO2/c1-18-15(17)14-5-3-2-4-13(14)12-8-6-11(10-16)7-9-12/h2-9H,10H2,1H3;Telmisartan Bromo Methyl Ester Impurity;2-[4-(Bromomethyl)Phenyl]Benzoic Acid Methyl Ester

Suppliers and Price of Methyl 2-[4-(bromomethyl)phenyl]benzoate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4’-Bromomethylbiphenyl-2-carboxylicAcid,MethylEster
2g
$ 240.00

TRC
4’-Bromomethylbiphenyl-2-carboxylicAcid,MethylEster
1g
$ 135.00

TCI Chemical
Methyl 2-[4-(Bromomethyl)phenyl]benzoate >98.0%(GC)
25g
$ 114.00

TCI Chemical
Methyl 2-[4-(Bromomethyl)phenyl]benzoate >98.0%(GC)
5g
$ 38.00

Frontier Specialty Chemicals
Methyl4'-(bromomethyl)biphenyl-2-carboxylate 98%
100g
$ 505.00

Frontier Specialty Chemicals
Methyl4'-(bromomethyl)biphenyl-2-carboxylate 98%
5g
$ 50.00

Frontier Specialty Chemicals
Methyl4'-(bromomethyl)biphenyl-2-carboxylate 98%
25g
$ 153.00

Crysdot
Methyl4'-(bromomethyl)-[1,1'-biphenyl]-2-carboxylate 97%
500g
$ 344.00

Biosynth Carbosynth
4'-Bromomethylbiphenyl-2-carboxylic acid, methyl ester
100 g
$ 200.00

Biosynth Carbosynth
4'-Bromomethylbiphenyl-2-carboxylic acid, methyl ester
50 g
$ 150.00

Total 182 raw suppliers

Chemical Property of Methyl 2-[4-(bromomethyl)phenyl]benzoate Edit

Chemical Property:

Appearance/Colour:off-white solid
Vapor Pressure:0.001-0.002Pa at 20-25℃
Melting Point:56 °C
Boiling Point:412.8 °C at 760 mmHg
Flash Point:203.5 °C
PSA：26.30000
Density:1.374 g/cm³
LogP:4.03510
Storage Temp.:-20°C Freezer, Under Inert Atmosphere
Solubility.:soluble in Toluene
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:304.00989
Heavy Atom Count:18
Complexity:272

Purity/Quality:

98.0% ^*data from raw suppliers

4’-Bromomethylbiphenyl-2-carboxylicAcid,MethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=CC=C1C2=CC=C(C=C2)CBr

Technology Process of Methyl 2-[4-(bromomethyl)phenyl]benzoate

There total 32 articles about Methyl 2-[4-(bromomethyl)phenyl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.6%

: 114772-34-8
methyl 4'-methylbiphenyl-2-carboxylate

: C₁₅H₁₂Br₂O₂

: 114772-38-2
Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Guidance literature:: With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; 2,2'-azobis(isobutyronitrile); In chloroform; at 60 - 65 ℃;
DOI:10.1021/op060200g

Reference yield: 90.0%

: 114772-34-8
methyl 4'-methylbiphenyl-2-carboxylate

: 114772-38-2
Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Guidance literature:: With N-Bromosuccinimide; In dichloromethane; at 25 ℃; for 5h; Temperature; Irradiation; Large scale;

Reference yield: 84.4%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 16605-99-5
biphenyl-2-carboxylic acid methyl ester

: 114772-38-2
Methyl 4'-(bromomethyl)biphenyl-2-carboxylate

Guidance literature:: formaldehyd; biphenyl-2-carboxylic acid methyl ester; With zinc dibromide; In tetrachloromethane; at 25 - 30 ℃; for 0.333333h;

With phosphorus tribromide; In tetrachloromethane;