Tripropylamine

Base Information

• Chemical Name: Tripropylamine
• CAS No.: 102-69-2
• Deprecated CAS: 112488-51-4
• Molecular Formula: C9H21N
• Molecular Weight: 143.272
• Hs Code.: 29211980
• European Community (EC) Number: 203-047-7
• UN Number: 2260
• UNII: 06S624V3U2
• DSSTox Substance ID: DTXSID9021849
• Nikkaji Number: J26.188B
• Wikidata: Q1637944
• Metabolomics Workbench ID: 45593
• Mol file: 102-69-2.mol

Synonyms:tri-n-propylamine;tripropylamine

Chemical Property of Tripropylamine

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 2.9 mm Hg ( 20 °C)
• Melting Point: -93.5 °C(lit.)
• Refractive Index: n20/D 1.416(lit.)
• Boiling Point: 158.1 °C at 760 mmHg
• PKA: pK1:10.66(+1) (25°C)
• Flash Point: 36.7 °C
• PSA: 3.24000
• Density: 0.777 g/cm³
• LogP: 2.51840
• Storage Temp.: Flammables area
• Sensitive.: Hygroscopic
• Solubility.: 0.483g/l
• Water Solubility.: 2.6 g/L (20 ºC)
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 143.167399674
• Heavy Atom Count: 10
• Complexity: 47.5
• Transport DOT Label: Flammable Liquid Corrosive

Purity/Quality:

99%min ^*data from raw suppliers

N,N-Dipropyl-1-propanamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T,Xn,C
• Statements: 10-20/21-25-34-52/53-23/25-21
• Safety Statements: 26-36/37/39-45-16-61-57-36/37/38

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCN(CCC)CCC
• Uses: Tri-n-propylamine is used as an chemical intermediate, organic solvent. It is used in the preparation of chemical compounds such as dyes, drugs, catalyst & other uses. It is used together with ruthenium in the electrochemiluminescence. Oxo feed stock, lubricant additive, plasticizers, nonyl phenol.

Technology Process of Tripropylamine

There total 68 articles about Tripropylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ethene (74-85-1) + carbon monoxide (201230-82-2) + di-n-propylamine (142-84-7) → tri-n-propylamine (102-69-2)

Guidance literature:

di(rhodium)tetracarbonyl dichloride; In ethanol; at 115 ℃; for 1.5h; under 37503 Torr;

DOI:10.1016/0022-328X(89)87190-6

Reference yield: 98.0%

propylamine (107-10-8,42939-71-9) + ethene (74-85-1) + carbon monoxide (201230-82-2) → tri-n-propylamine (102-69-2) + di-n-propylamine (142-84-7)

Guidance literature:

di(rhodium)tetracarbonyl dichloride; In ethanol; at 119 ℃; for 1h; under 44253.5 Torr;

DOI:10.1016/0022-328X(89)87190-6

Reference yield: 95.0%

propan-1-ol (71-23-8) + octanol (111-87-5) + propiononitrile (107-12-0) → tri-n-propylamine (102-69-2) + Dipropyloctylamin (99209-95-7)

Guidance literature:

With hydrogen; copper; at 240 ℃; under 7600 Torr;

upstream raw materials:

propan-1-ol

propionaldehyde oxime

tetrapropylammonium

tripropylamine oxide

Downstream raw materials:

tetrapropylammonium iodide

tri-n-propyl-methylammonium iodide

allyltripropylammonium bromide

Perfluorotripropylamine

Refernces

• 1、 Grovenstein,Stevenson. "". . p. 4850,4853. Retrieved 1959.
• 2、 Li, Yi,Gong, Yutong,Xu, Xuan,Zhang, Pengfei,Li, Haoran,Wang, Yong. "A practical and benign synthesis of amines through Pd@mpg-C 3N4 catalyzed reduction of nitriles". . p. 9 - 12. Retrieved 2012.
• 3、 Pawelka, Zbigniew,Zeegers-Huyskens, Therese. "Alkyl substituent effect on the polarity of phenols-tri-n-alkylamine complexes". . p. 1012 - 1018. Retrieved 2003.
• 4、 Janiak, Tadeusz,Blazejowski, Jerzy. "". . p. 93 - 112. Retrieved 1989.
• 5、 Guidry, Trent F.,Price, Geoffrey L.. "The conversion of 1-propanamine on copper-containing MFI and BEA zeolites prepared by aqueous and vapor ion-exchange". . p. 16 - 27. Retrieved 1999.
• 6、 Jacobson, D. B.. "Protonation Dynamics of 2(μ-CO)(μ-C=CH2) and Decomposition Processes for 2(μ-CO)(μ-C=CH2)H(+) in the Gas Phase". . p. 1626 - 1634. Retrieved 1989.
• 7、 García-Domínguez, Andrés,Gonzalez, Jorge A.,Leach, Andrew G.,Lloyd-Jones, Guy C.,Nichol, Gary S.,Taylor, Nicholas P.. "A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics". supporting information. . Retrieved 2022/01/04.
• 8、 Popov, Yu. V.,Mokhov,Latyshova,Nebykov,Panov,Pletneva, M. Yu.. "Colloid and nanosized catalysts in organic synthesis: XVI.1 Continuous hydrogenation of carbonitriles catalyzed by nickel nanoparticles applied on a support". . p. 2276 - 2281. Retrieved 2017/11/24.