IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Base Information

• Chemical Name: IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄
• CAS No.: 132939-88-9
• Molecular Formula: BF₄*C₇₁H₆₀AuIrO₃OsP₅
• Molecular Weight: 1782.32
• Mol file: 132939-88-9.mol

Synonyms:IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Chemical Property of IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄

There total 1 articles about IrOs(H)(AuP(C₆H₅)3)(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-) = {IrOs(H)(AuP(C₆H₅)3)(CO)3(((C₆H₅)2P)2CH₂)2}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

silver tetrafluoroborate (14104-20-2) + (triphenylphosphine)gold(I) chloride (14243-64-2) + IrOs(H)2(CO)3((C6H4)C6H5PCH2P(C6H5)2)((C6H5)2PCH2P(C6H5)2) (132959-03-6) → IrOs(H)(AuP(C6H5)3)(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)(AuP(C6H5)3)(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-88-9)

Guidance literature:

In tetrahydrofuran; acetone; byproducts: AgCl; (Ar); added a soln. of Au-compound in acetone to AgBF4; stirred for 1 h; filtered; evapd.; dissolved in THF; added to stirred soln. of Ir-complex; stirred for 1 h; filtered; evapd.; recrystd. from CH2Cl2/Et2O at room temp.; elem. anal.;

DOI:10.1021/om00051a018

Reference yield: 80.0%

IrOs(H)(AuP(C6H5)3)(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = {IrOs(H)(AuP(C6H5)3)(CO)3(((C6H5)2P)2CH2)2}BF4 (132939-88-9) → IrOs(H)I(CO)3((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-)*C4H8O = {IrOs(H)I(CO)3(((C6H5)2P)2CH2)2}BF4*C4H8O (132959-05-8)

Guidance literature:

With iodine; In dichloromethane; byproducts: AuPPh3I; (Ar); added dropwise a soln. of I2 to stirred soln. of Ir-complex over 1 h; stirred for 1 h; evapd. (vac.); washed with Et2O; recrystd. from THF/Et2O; elem. anal.;

DOI:10.1021/om00051a018

upstream raw materials:

silver tetrafluoroborate

(triphenylphosphine)gold(I) chloride

IrOs(H)2(CO)3((C₆H₄)C₆H₅PCH₂P(C₆H₅)2)((C₆H₅)2PCH₂P(C₆H₅)2)

Downstream raw materials:

IrOs(H)I(CO)3((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)*C₄H₈O = {IrOs(H)I(CO)3(((C₆H₅)2P)2CH₂)2}BF₄*C₄H₈O

Refernces