Dichloro(1,5-cyclooctadien)ruthenium(II) polymer

Base Information

• Chemical Name: Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
• CAS No.: 50982-13-3
• Molecular Formula: C₈H₁₂Cl₂Ru
• Molecular Weight: 280.159
• Hs Code.: 28439000
• Mol file: 50982-13-3.mol

Synonyms:1,5-Cyclooctadiene, ruthenium complex;(1,5-Cyclooctadiene)ruthenium(II) chloride polymer;1,5-Cyclooctadienedichlororuthenium;Dichloro(1,5-cyclooctadiene)ruthenium;ruthenium(2+) dichloride - (1Z,5Z)-cycloocta-1,5-diene (1:1);(1Z,5Z)-Cycloocta-1,5-diene - dichlororuthenium (1:1);1,5-cyclooctadiene, (1Z,5Z)-, ruthenium(2+) salt, hydrochloride (1:1:2);Ruthenium(2+) chloride (1Z,5Z)-cycloocta-1,5-diene (1:2:1);

Chemical Property of Dichloro(1,5-cyclooctadien)ruthenium(II) polymer

Chemical Property:

• Vapor Pressure: 4.25mmHg at 25°C
• Melting Point: 200°C (dec.)
• Boiling Point: 153.5 °C at 760 mmHg
• Flash Point: 31.7 °C
• PSA: 0.00000
• LogP: -3.31920
• Sensitive.: Hygroscopic

Purity/Quality:

99% ^*data from raw suppliers

Dichloro (1,5-cyclooctadiene)ruthenium(III) polymer, Ru 34.7% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 52/53-36/37/38
• Safety Statements: 61-37/39-26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dichloro(1,5-cyclooctadien)ruthenium(II) polymer

There total 2 articles about Dichloro(1,5-cyclooctadien)ruthenium(II) polymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

rhodium(III) chloride hydrate + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3)

Guidance literature:

In ethanol; for 72h; Inert atmosphere; Reflux;

DOI:10.1039/c6dt03792e

Reference yield:

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) + ruthenium(III) chloride trihydrate → dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3)

Guidance literature:

In ethanol; at 85 ℃; for 5h; Inert atmosphere;

Reference yield: 82.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3) + tris[diphenylphosphinomethyl]phenylsilane (1609574-91-5) → C90H82Cl3P6Ru2Si2(1+)*Cl(1-)

Guidance literature:

In toluene; at 125 ℃; for 21h;

DOI:10.1002/ejic.201301074

upstream raw materials:

1,5-cis,cis-cyclooctadiene

cyclo-octa-1,5-diene

Downstream raw materials:

bis(acetato){2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}ruthenium(II)

(η4-cyclooctadiene)Ru(η2-PhNC(H)=NPh)2

Refernces

• 1、 Poulsen, Bj?rn C.,Estalayo-Adrián, Sandra,Blasco, Salvador,Bright, Sandra A.,Kelly, John M.,Williams, D. Clive,Gunnlaugsson, Thorfinnur. "Luminescent ruthenium polypyridyl complexes with extended 'dppz' like ligands as DNA targeting binders and cellular agents". supporting information. p. 18208 - 18220. Retrieved 2016/11/25.