Iron(II) phthalocyanine

Base Information

• Chemical Name: Iron(II) phthalocyanine
• CAS No.: 132-16-1
• Molecular Formula: C32H16FeN8
• Molecular Weight: 568.38
• Hs Code.: 29319090
• European Community (EC) Number: 205-047-2
• Mol file: 132-16-1.mol

Synonyms:ferrous phthalocyanine;iron(II) phthalocyanine

Chemical Property of Iron(II) phthalocyanine

Chemical Property:

• Appearance/Colour: Dark purple, green or black powder
• Melting Point: >300 °C
• PSA: 84.02000
• Density: 0.326[at 20℃]
• LogP: 1.46190
• Water Solubility.: It is insoluble in water. It is soluble in conc. sulfuric acid.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 568.084728
• Heavy Atom Count: 41
• Complexity: 1080

Purity/Quality:

99% ^*data from raw suppliers

Iron(II) phthalocyanine ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Dyes -> Phthalocyanine Dyes
• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Fe+2]
• Uses: Iron phthalocyanine is been investigated as organic electroluminescence materials for the applications in organic solar cells, biosensitizers and display devices such as OLED(Organic Light Emiting Diode), OTFT(Organic Thin Film Transistor), Wearable Display, and e-paper. It is also used in the formation of new type of catalyst.

Technology Process of Iron(II) phthalocyanine

There total 51 articles about Iron(II) phthalocyanine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

iron(II) chloride tetrahydrate + urea (57-13-6) + phthalonitrile (91-15-6) → iron(II) phthalocyanine (132-16-1)

Guidance literature:

With ammonium molybdate; at 110 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1142/S1088424612501106

Reference yield: 89.0%

phthalic anhydride (85-44-9) + iron(II) chloride tetrahydrate + urea (57-13-6) → iron(II) phthalocyanine (132-16-1)

Guidance literature:

With ammonium molybdate; at 130 ℃; for 0.0833333h; Microwave irradiation;

DOI:10.1142/S1088424612501106

Reference yield: 88.0%

phthalimide (136918-14-4,85-41-6) + iron(II) chloride tetrahydrate + urea (57-13-6) → iron(II) phthalocyanine (132-16-1)

Guidance literature:

With ammonium molybdate; at 120 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1142/S1088424612501106

upstream raw materials:

bis(pyridine)phthalocyanatoiron(II)

phthalic anhydride

urea

ferrocene

Downstream raw materials:

pyrographite

iron

iron(III)phthalocyanine chloride

bis(2-methylphenylisocyanide)(phthalocyaninato)iron(II)

Refernces

• 1、 Bata, Pter,Notheisz, Ferenc,Kluson, Peter,Zsigmond, gnes. "Iron phthalocyanine as new efficient catalyst for catalytic transfer hydrogenation of simple aldehydes and ketones". . p. 45 - 49. Retrieved 2015.
• 2、 Langton, John,Day, Peter. "". . . Retrieved 1982.
• 3、 Janczak, Jan,Kubiak, Ryszard. "Synthesis, thermal stability and structural characterisation of iron(II) phthalocyanine complex with 4-cyanopyridine". . p. 2997 - 3002. Retrieved 2007.
• 4、 Calderazzo, Fausto,Pampaloni, Guido,Vitali, Dario,Pelizzi, Giancarlo,Collamati, Ines,et al.. "CARBONYL DERIVATIVES OF PHTHALOCYANINATOIRON(II), ESPECIALLY THOSE CONTAINING GROUP VI AXIAL DONOR ATOMS. CRYSTAL AND MOLECULAR STRUCTURE OF CARBONYL(N,N-DIMETHYLFORMAMIDE)PHTHALOCYANINATOIRON(II) AND MOESSBAUER STUDIES OF SOME OF THE PRODUCTS". . p. 217 - 242. Retrieved 1980.
• 5、 Suvorova,Verle,Bazyakina,Kutyreva,Makarov,Shchupak. "Reactions of ferrocene with phthalonitrile on the surface of oxide powders". . p. 649 - 653. Retrieved 2006.
• 6、 Wei, Ho-Hsiang,Shyu, Huey-Lih. "". . p. 979 - 982. Retrieved 1985.
• 7、 Bell, Norman A.,Brooks, John S.,Forder, Susan D.,Robinson, Jacqueline K.,Thorpe, Stephen C.. "Backscatter Fe-57 M?ssbauer studies of iron(II) phthalocyanine". . p. 115 - 118. Retrieved 2002.
• 8、 Cariati, Franco,Morazzoni, Franca,Zocchi, Marcello. "". . . Retrieved 1978.
• 9、 Edmondson, Stephen J.,Hill, Jon S.,Isaacs, Neil S.,Mitchell, Philip C. H.. "High-pressure Conditions for Improved Synthesis of Phthalocyanines". . p. 1115 - 1118. Retrieved 1990.
• 10、 Denekamp, Ilse M.,Veenstra, Florentine L.P.,Jungbacker, Peter,Rothenberg, Gadi. "A simple synthesis of symmetric phthalocyanines and their respective perfluoro and transition-metal complexes". . . Retrieved 2019.