Silicon dihydroxyl phthalocyanine

Base Information

• Chemical Name: Silicon dihydroxyl phthalocyanine
• CAS No.: 19333-15-4
• Molecular Formula: C32H18 N8 O2 Si
• Molecular Weight: 574.633
• European Community (EC) Number: 621-545-6
• DSSTox Substance ID: DTXSID70399115
• Mol file: 19333-15-4.mol

Synonyms:Silicon dihydroxyl phthalocyanine;19333-15-4;Silicon phthalocyanine dihydroxide;38,38-dihydroxy-9,18,27,36,37,39,40,41-octaza-38-siladecacyclo[17.17.3.110,17.128,35.02,7.08,37.011,16.020,25.026,39.029,34]hentetraconta-1,3,5,7,9,11,13,15,17(41),18,20,22,24,26,28(40),29,31,33,35-nonadecaene;Silicon,dihydroxy[29H,31H-phthalocyaninato(2-)-kN29,kN30,kN31,kN32]-,(OC-6-12)-;dihydroxy silicon phthalocyanine;SCHEMBL11978997;DTXSID70399115;SILICONPHTHALOCYANINEDIHYDROXIDE;AKOS002375249;AKOS015914483;FT-0776013;Silicon phthalocyanine dihydroxide, Dye content 75 %

Chemical Property of Silicon dihydroxyl phthalocyanine

Chemical Property:

• PSA: 124.48000
• LogP: -0.03040
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 574.13219838
• Heavy Atom Count: 43
• Complexity: 1240

Purity/Quality:

99% ^*data from raw suppliers

Silicon phthalocyanine dihydroxide Dye content 75 % ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=C5C=CC=CC5=C6N4[Si](N7C(=NC2=N3)C8=CC=CC=C8C7=NC9=NC(=N6)C1=CC=CC=C19)(O)O

Technology Process of Silicon dihydroxyl phthalocyanine

There total 12 articles about Silicon dihydroxyl phthalocyanine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

C88H110N8O28Si → dihydroxy silicon(IV) phthalocyanine (19333-15-4)

Guidance literature:

C₈₈H₁₁₀N₈O₂₈Si; With sulfuric acid; In water; at 20 ℃; for 4h;

With pyridine; ammonium hydroxide; In water; at 20 ℃; for 20h;

Reference yield: 80.0%

phthalocyanine silicon(IV) dichloride (19333-10-9) → dihydroxy silicon(IV) phthalocyanine (19333-15-4)

Guidance literature:

With water; sodium hydroxide; In pyridine; for 1h; Reflux;

Reference yield: 79.0%

isoindole-1,3-diylidenediamine (160956-25-2,160956-26-3,160956-27-4,160956-28-5,160956-29-6) → dihydroxy silicon(IV) phthalocyanine (19333-15-4)

Guidance literature:

isoindole-1,3-diylidenediamine; With tetrachlorosilane; 1,8-diazabicyclo[5.4.0]undec-7-ene; In sulfolane; at 150 ℃; for 8h;

With water; In sulfolane; at 80 ℃; for 3h; Cooling with ice;

upstream raw materials:

silicon(IV) phthalocyanine dichloride

phthalocyanine silicon(IV) dichloride

water

isoindole-1,3-diylidenediamine

Downstream raw materials:

C₄₂H₄₄N₁₀O₂Si₃

{bis-[bis-(p-N,N-dimethylaminophenyl)]-3-(piperidine-1-yl)propylsilyloxy} silicon(IV) phthalocyanine

{bis-[3-(m-N,N-dimethylaminophenyloxy)propyl-dipropylsilyloxyl]}silicon(IV) phthalocyanine

{bis-[bis-(p-N,N-dimethylaminophenyl)]propylsilyloxyl} silicon(IV) phthalocyanine

Refernces

• 1、 Ando, Kanta,Goto, Yuto,Harada, Mei,Kobayashi, Masato,Ogawa, Mikako,Takakura, Hideo,Taketsugu, Tetsuya,Tsuneda, Takao. "Theoretical and Experimental Studies on the Near-Infrared Photoreaction Mechanism of a Silicon Phthalocyanine Photoimmunotherapy Dye: Photoinduced Hydrolysis by Radical Anion Generation". . . Retrieved 2020.
• 2、 Dang, Minh-Trung,Grant, Trevor M.,Yan, Han,Seferos, Dwight S.,Lessard, Beno?t H.,Bender, Timothy P.. "Bis(tri-n-alkylsilyl oxide) silicon phthalocyanines: A start to establishing a structure property relationship as both ternary additives and non-fullerene electron acceptors in bulk heterojunction organic photovoltaic devices". . p. 12168 - 12182. Retrieved 2017/07/10.